VCl₂(N-2,6-Me₂C₆H₃)(O-2,6-iPr₂C₆H₃)

Base Information

• Chemical Name: VCl₂(N-2,6-Me₂C₆H₃)(O-2,6-iPr₂C₆H₃)
• CAS No.: 330801-43-9
• Molecular Formula: C₂₀H₂₆Cl₂NOV
• Molecular Weight: 418.28
• Mol file: 330801-43-9.mol

Synonyms:

Chemical Property of VCl₂(N-2,6-Me₂C₆H₃)(O-2,6-iPr₂C₆H₃)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of VCl₂(N-2,6-Me₂C₆H₃)(O-2,6-iPr₂C₆H₃)

There total 1 articles about VCl₂(N-2,6-Me₂C₆H₃)(O-2,6-iPr₂C₆H₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(2,6-xylylimido) vanadium trichloride + 2,6-diisopropylphenol (2078-54-8) → VCl2(N-2,6-Me2C6H3)(O-2,6-iPr2C6H3) (330801-43-9)

Guidance literature:

In hexane; dropwise addn. of org. compd. to hexane soln. of V compd. at -30°C, warmed to room temp., stirred for 10 h; solvent removed in vac., layered with n-hexane at -30°C , solid washed with cold hexane, dried in vac.; elem. anal.;

DOI:10.1246/cl.2001.36

Reference yield:

LiCH2SiMe3 + VCl2(N-2,6-Me2C6H3)(O-2,6-iPr2C6H3) (330801-43-9) → V(C6H3(CH3)2N)(CH2Si(CH3)3)2(OC6H3(CH(CH3)2)2)

Guidance literature:

In hexane; (N2, Schlenk) LiCH2Si(CH3)3 was added to a soln. of complex in hexane at-30°C, the mixt. was slowly warmed to room temp., stirred for 4 h; filtered, the solvent was pumped off;

DOI:10.1021/om800284d

upstream raw materials:

2,6-diisopropylphenol