bis(pentafluorophenyl)zinc toluene adduct (1/1)

Base Information

• Chemical Name: bis(pentafluorophenyl)zinc toluene adduct (1/1)
• CAS No.: 363596-50-3
• Molecular Formula: C₇H₈*C₁₂F₁₀Zn
• Molecular Weight: 491.647
• Mol file: 363596-50-3.mol

Synonyms:

Chemical Property of bis(pentafluorophenyl)zinc toluene adduct (1/1)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(pentafluorophenyl)zinc toluene adduct (1/1)

There total 1 articles about bis(pentafluorophenyl)zinc toluene adduct (1/1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.6%

tris(pentafluorophenyl)borate (1109-15-5) + di-tert-butylzinc (16636-96-7) + toluene (108-88-3,15644-74-3,16713-13-6) → bis(pentafluorophenyl)zinc toluene adduct (1/1) (363596-50-3,903499-23-0)

Guidance literature:

In toluene; under N2 atm. soln. B(C6F5)3 in toluene was treated with soln. ZnMe2 in toluene at room temp. and stirred for 30 min; volatiles were removed, residue was crystd. from light petroleum at -20°C; elem. anal.;

DOI:10.1021/om0103557

Reference yield: 99.0%

bis(pentafluorophenyl)zinc toluene adduct (1/1) (363596-50-3,903499-23-0) + tBu3PN2OB(C6F4F)3 → [tBu3PN2O(zinc)(C6F5)]2

Guidance literature:

In CH₂Cl₂; byproducts: B(C6H4F)3; soln. of Zn(C6F5)2*tol (0.185 mmol) and tBu3PN2OB(C6H4F)3 (0.184 mmol) stirred for 1 h at room temp.; hexane added, ppt. filtered, washed with hexane, dried in vac. for 2 h;

DOI:10.1002/anie.200905650

Reference yield: 99.0%

bis(pentafluorophenyl)zinc toluene adduct (1/1) (363596-50-3,903499-23-0) + [1,3-bis(2,4,6-trimethylphenyl)imidazol]-2-ylidene (141556-42-5) → (1,3-dimesitylimidazol-2-ylidene)Zn(C6F5)2

Guidance literature:

In toluene; at -35 - 20 ℃; Glovebox; Inert atmosphere;

DOI:10.1002/ejic.201300292

upstream raw materials:

tris(pentafluorophenyl)borate

di-tert-butylzinc

toluene

Downstream raw materials:

Zn(C₆F₅)2*C₆(CH₃)6

(C(C₆H₅)3)⁽¹⁺⁾*Zn(C₆F₅)3^(1-)=(C(C₆H₅)3)(Zn(C₆F₅)3)

bis(pentafluorophenyl)zinc pyrrolidine adduct (1/2)

bis(pentafluorophenyl)zinc tert-butylamine adduct (1/2)