1,2-bis(tricarbonylchromiophenyl)-1,2-diphenylethane

Base Information

• Chemical Name: 1,2-bis(tricarbonylchromiophenyl)-1,2-diphenylethane
• CAS No.: 117497-11-7
• Molecular Formula: C₃₂H₂₂Cr₂O₆
• Molecular Weight: 606.515
• Mol file: 117497-11-7.mol

Synonyms:

Chemical Property of 1,2-bis(tricarbonylchromiophenyl)-1,2-diphenylethane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 1,2-bis(tricarbonylchromiophenyl)-1,2-diphenylethane

There total 1 articles about 1,2-bis(tricarbonylchromiophenyl)-1,2-diphenylethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

n-butyl magnesium bromide (693-03-8) + benzhydroltricarbonylchromium(0) (12155-17-8) → (1,1-diphenylpentane)tricarbonylchromium (117579-59-6) + 1,2-bis(tricarbonylchromiophenyl)-1,2-diphenylethane (117558-89-1,117497-11-7)

Guidance literature:

With hexafluorophosphoric acid; In diethyl ether; dichloromethane; under N2, (Ph2CHOH)Cr(CO)3 dissolved in CH2Cl2, cooled to -40°C, HPF6 in ether added with stirring, after 1 min soln. of n-BuMgBr in ether added, after 5 min quenched with ice water; extd. with CH2Cl2, washed with water, dried over MgSO4, chromd. (SiO2, ether/hexane: 1/5); elem. anal.;

DOI:10.1016/0022-328X(87)87164-4

upstream raw materials:

n-butyl magnesium bromide

benzhydroltricarbonylchromium⁽⁰⁾