C₃₇H₃₈O₅Si

Base Information

• Chemical Name: C₃₇H₃₈O₅Si
• CAS No.: 936005-50-4
• Molecular Formula: C₃₇H₃₈O₅Si
• Molecular Weight: 590.791
• Mol file: 936005-50-4.mol

Synonyms:

Chemical Property of C₃₇H₃₈O₅Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₇H₃₈O₅Si

There total 6 articles about C₃₇H₃₈O₅Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C22H23O2SiN (936005-43-5) → C37H38O5Si (936005-50-4)

Guidance literature:

Multi-step reaction with 5 steps

1.1: 90 percent / tetrahydrofuran / 0.5 h / -20 - -10 °C

2.1: (+)-(Ipc)2BH / tetrahydrofuran / 37 h / 0 - 4 °C

2.2: H₂O₂; NaOH / tetrahydrofuran; H₂O / 0.17 h / 20 °C

3.1: 84 percent / PhI(OAc)2; TEMPO / CH₂Cl₂ / 3 h / 20 °C

4.1: LDA / tetrahydrofuran / 1 h / -78 °C

4.2: 88 percent / tetrahydrofuran / 0.33 h

5.1: 74 percent / PDC / CH₂Cl₂ / 72 h / 20 °C

With 2,2,6,6-tetramethyl-piperidine-N-oxyl; dipyridinium dichromate; [bis(acetoxy)iodo]benzene; L-diisopinocampheylborane; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane;

DOI:10.1002/ejoc.200601047

Reference yield:

C23H22O2Si (936005-46-8) → C37H38O5Si (936005-50-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: LDA / tetrahydrofuran / 1 h / -78 °C

1.2: 88 percent / tetrahydrofuran / 0.33 h

2.1: 74 percent / PDC / CH₂Cl₂ / 72 h / 20 °C

With dipyridinium dichromate; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane;

DOI:10.1002/ejoc.200601047

Reference yield:

C23H26O2Si (1026594-58-0) → C37H38O5Si (936005-50-4)

Guidance literature:

Multi-step reaction with 3 steps

1.1: 84 percent / PhI(OAc)2; TEMPO / CH₂Cl₂ / 3 h / 20 °C

2.1: LDA / tetrahydrofuran / 1 h / -78 °C

2.2: 88 percent / tetrahydrofuran / 0.33 h

3.1: 74 percent / PDC / CH₂Cl₂ / 72 h / 20 °C

With 2,2,6,6-tetramethyl-piperidine-N-oxyl; dipyridinium dichromate; [bis(acetoxy)iodo]benzene; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane;

DOI:10.1002/ejoc.200601047

upstream raw materials:

C₂₂H₂₃O₂SiN

C₂₃H₂₂OSi

C₂₃H₂₆O₂Si

C₂₃H₂₂O₂Si