Rh((C₆H₅)2PCH₂P(C₆H₅)2)2Cl

Base Information

Chemical Name:Rh((C₆H₅)2PCH₂P(C₆H₅)2)2Cl
CAS No.:70196-18-8
Molecular Formula:C₅₀H₄₄ClP₄Rh
Molecular Weight:907.153
Hs Code.:

Rh((C<sub>6</sub>H<sub>5</sub>)2PCH<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)2)2Cl

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Chemical Property of Rh((C₆H₅)2PCH₂P(C₆H₅)2)2Cl

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Technology Process of Rh((C₆H₅)2PCH₂P(C₆H₅)2)2Cl

There total 1 articles about Rh((C₆H₅)2PCH₂P(C₆H₅)2)2Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 14694-95-2
tris(triphenylphosphine)rhodium(l) chloride

: 2071-20-7
bis-diphenylphosphinomethane

: 70196-18-8,73188-61-1
Rh((C₆H₅)2PCH₂P(C₆H₅)2)2Cl

Guidance literature:: In toluene; under oxygen-free N2; an excess of diphoshine was added to Rh-complex at room temp. and the mixt. stirred for 4 d; soln. evapd., residue extd. twice with toluene, filtered and cooled to -20°C; elem. anal.;
DOI:10.1016/0277-5387(82)80008-9

Reference yield: 90.0%

: 70196-18-8,73188-61-1
Rh((C₆H₅)2PCH₂P(C₆H₅)2)2Cl

: sodium cyclopentadienide

: 86251-23-2
bis(diphenylphosphino)methane-η5-cyclopentadienylrhodium(I)

Guidance literature:: In tetrahydrofuran; byproducts: (C6H5)2PCH2P(C6H5)2; under oxygen-free N2; slight excess of NaC5H5 was added to Rh-complex (both in THF) at 0°C, soln. was warmed and stirred at room temp. for 18 h; soln. evapd., residue extd. twice into toluene and filtered; filtrate concd., Et2O added and the soln. cooled at -20°C; free dppm crystd. at first and then, after further concn., the complex; elem. anal.;
DOI:10.1016/0277-5387(82)80008-9

Reference yield: 80.0%

: 70196-18-8,73188-61-1
Rh((C₆H₅)2PCH₂P(C₆H₅)2)2Cl

: 917-54-4
methyllithium

: bis[bis(diphenylphosphino)methane]methylrhodium(I)

Guidance literature:: In toluene; under oxygen-free N2; LiMe was added to Rh-complex in toluene at 0°C, soln. was warmed and stirred at room temp. for 18 h; soln. evapd., residue extd. twice into toluene and filtered; filtrate concd., Et2O added and the soln. cooled at -20°C; elem. anal.;
DOI:10.1016/0277-5387(82)80008-9