tetraphenylphosphonium [(cyclopentadienyl)tris(diethylphosphito-P)cobalt-O,O',O'']trichlororhodate

Base Information

• Chemical Name: tetraphenylphosphonium [(cyclopentadienyl)tris(diethylphosphito-P)cobalt-O,O',O'']trichlororhodate
• CAS No.: 105618-21-1
• Molecular Formula: C₁₇H₃₅Cl₃CoO₉P₃Rh*C₂₄H₂₀P
• Molecular Weight: 1084.04
• Mol file: 105618-21-1.mol

Synonyms:

Chemical Property of tetraphenylphosphonium [(cyclopentadienyl)tris(diethylphosphito-P)cobalt-O,O',O'']trichlororhodate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetraphenylphosphonium [(cyclopentadienyl)tris(diethylphosphito-P)cobalt-O,O',O'']trichlororhodate

There total 1 articles about tetraphenylphosphonium [(cyclopentadienyl)tris(diethylphosphito-P)cobalt-O,O',O'']trichlororhodate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

rhodium(III) trichloride hydrate + [((C5H5)Co(P(O)(OC2H5)2)3Na)3(H2O)2]*2H2O + tetraphenyl phosphonium chloride (2001-45-8) → di-μ-chlorobis([(cyclopentadienyl)tris(diethylphosphito-P)cobalt-O,O',O'']chlororhodium) + tetraphenylphosphonium [(cyclopentadienyl)tris(diethylphosphito-P)cobalt-O,O',O'']trichlororhodate (105618-21-1)

Guidance literature:

In tetrahydrofuran; water; under dry N2; RhCl3*xH2O added to Co-compd. in THF, react. time 24 h, ppt. filtered off, washed (THF), dried (vac.), dissolved in H2O, pptn. byaddn. of satd. aq. soln. of PPh4Cl; sepd. by centrifugation, washed (H2O), dried (vac.), recrystn. from acetone/ether, elem. anal.;

DOI:10.1021/ja00235a025

upstream raw materials:

tetraphenyl phosphonium chloride