p-tolyl 2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-6-O-(2,2,2-trichloroethylsulfuryl)-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-1-thio-α-L-idopyranoside

Base Information

Chemical Name:p-tolyl 2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-6-O-(2,2,2-trichloroethylsulfuryl)-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-1-thio-α-L-idopyranoside
CAS No.:1334709-90-8
Molecular Formula:C₄₈H₅₈Cl₃N₃O₁₃S₂Si
Molecular Weight:1083.58
Hs Code.:

p-tolyl 2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-6-O-(2,2,2-trichloroethylsulfuryl)-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-1-thio-α-L-idopyranoside

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Chemical Property of p-tolyl 2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-6-O-(2,2,2-trichloroethylsulfuryl)-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-1-thio-α-L-idopyranoside

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Technology Process of p-tolyl 2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-6-O-(2,2,2-trichloroethylsulfuryl)-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-1-thio-α-L-idopyranoside

There total 5 articles about p-tolyl 2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-6-O-(2,2,2-trichloroethylsulfuryl)-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-1-thio-α-L-idopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1334709-89-5
p-tolyl 2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-6-O-(2,2,2-trichloroethylsulfuryl)-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-p-methoxybenzyl-1-thio-α-L-idopyranoside

: 1334709-90-8
p-tolyl 2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-6-O-(2,2,2-trichloroethylsulfuryl)-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-1-thio-α-L-idopyranoside

Guidance literature:: With water; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; at 0 - 20 ℃; for 6h; Inert atmosphere;
DOI:10.1002/chem.201101108

Reference yield:

: 1242437-11-1
p-tolyl 2-O-benzoyl-3-O-benzyl-6-O-p-methoxybenzyl-1-thio-α-L-idopyranoside

: 1334709-90-8
p-tolyl 2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-6-O-(2,2,2-trichloroethylsulfuryl)-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-1-thio-α-L-idopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: silver trifluoromethanesulfonate / diethyl ether; dichloromethane / 0.08 h / -78 °C / Inert atmosphere; Molecular sieve

1.2: 0.08 h / -78 °C / Inert atmosphere

1.3: 2 h / -78 - -20 °C / Inert atmosphere

2.1: methanol; magnesium hydroxide / dichloromethane / 6 h / 0 - 20 °C / Inert atmosphere

3.1: 1,2-dimethyl-1H-imidazole / dichloromethane / 4 h / 0 - 35 °C / Inert atmosphere

4.1: water; 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 6 h / 0 - 20 °C / Inert atmosphere

With 1,2-dimethyl-1H-imidazole; methanol; magnesium hydroxide; water; silver trifluoromethanesulfonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In diethyl ether; dichloromethane;
DOI:10.1002/chem.201101108

Reference yield:

: 1242437-13-3
p-tolyl 6-O-acetyl-2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-1-thio-β-D-glucopyranoside

: 1334709-90-8
p-tolyl 2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-6-O-(2,2,2-trichloroethylsulfuryl)-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-1-thio-α-L-idopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: silver trifluoromethanesulfonate / diethyl ether; dichloromethane / 0.08 h / -78 °C / Inert atmosphere; Molecular sieve

1.2: 0.08 h / -78 °C / Inert atmosphere

1.3: 2 h / -78 - -20 °C / Inert atmosphere

2.1: methanol; magnesium hydroxide / dichloromethane / 6 h / 0 - 20 °C / Inert atmosphere

3.1: 1,2-dimethyl-1H-imidazole / dichloromethane / 4 h / 0 - 35 °C / Inert atmosphere

4.1: water; 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 6 h / 0 - 20 °C / Inert atmosphere

With 1,2-dimethyl-1H-imidazole; methanol; magnesium hydroxide; water; silver trifluoromethanesulfonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In diethyl ether; dichloromethane;
DOI:10.1002/chem.201101108