[(μ-acetato)bis(μ-benzohydroxamate)bis(N,N,N',N'-tetramethylethylenediamine)dinickel(II)] trifluoromethanesulfonate monohydrate

Base Information

• Chemical Name: [(μ-acetato)bis(μ-benzohydroxamate)bis(N,N,N',N'-tetramethylethylenediamine)dinickel(II)] trifluoromethanesulfonate monohydrate
• CAS No.: 857680-35-4
• Molecular Formula: CF₃O₃S*C₂₈H₄₇N₆Ni₂O₆*H₂O
• Molecular Weight: 848.183
• Mol file: 857680-35-4.mol

Synonyms:

Chemical Property of [(μ-acetato)bis(μ-benzohydroxamate)bis(N,N,N',N'-tetramethylethylenediamine)dinickel(II)] trifluoromethanesulfonate monohydrate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(μ-acetato)bis(μ-benzohydroxamate)bis(N,N,N',N'-tetramethylethylenediamine)dinickel(II)] trifluoromethanesulfonate monohydrate

There total 2 articles about [(μ-acetato)bis(μ-benzohydroxamate)bis(N,N,N',N'-tetramethylethylenediamine)dinickel(II)] trifluoromethanesulfonate monohydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.8%

[acetato(N,N,N',N'-tetramethylethylenediamine)diaquanickel(II)] trifluoromethanesulfonate monohydrate (857504-44-0) + Benzohydroxamic acid (495-18-1) → [(μ-acetato)bis(μ-benzohydroxamate)bis(N,N,N',N'-tetramethylethylenediamine)dinickel(II)] trifluoromethanesulfonate monohydrate (857680-35-4)

Guidance literature:

In methanol; N2, equimol., stirred for 30 min; filtered, solvent removed (vac.), recrystd. (CH3CN/diethyl ether); elem.anal.;

DOI:10.1016/j.ica.2005.01.029

Reference yield:

[bis(μ-acetato)(μ-aqua)bis(acetato)bis(N,N,N',N'-tetramethylethylenediamine)dinickel(II)] (65652-94-0) → [(μ-acetato)bis(μ-benzohydroxamate)bis(N,N,N',N'-tetramethylethylenediamine)dinickel(II)] trifluoromethanesulfonate monohydrate (857680-35-4)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane

2: methanol

In methanol; dichloromethane;

DOI:10.1016/j.ica.2005.01.029

upstream raw materials:

[acetato(N,N,N',N'-tetramethylethylenediamine)diaquanickel(II)] trifluoromethanesulfonate monohydrate

Benzohydroxamic acid

[bis(μ-acetato)(μ-aqua)bis(acetato)bis(N,N,N',N'-tetramethylethylenediamine)dinickel(II)]