Mo(CO)5(η1-1,2-bis(diphenylphosphino)ethane)

Base Information

Chemical Name:Mo(CO)5(η1-1,2-bis(diphenylphosphino)ethane)
CAS No.:52901-70-9
Molecular Formula:C₃₁H₂₄MoO₅P₂
Molecular Weight:634.416
Hs Code.:

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Chemical Property of Mo(CO)5(η1-1,2-bis(diphenylphosphino)ethane)

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Technology Process of Mo(CO)5(η1-1,2-bis(diphenylphosphino)ethane)

There total 1 articles about Mo(CO)5(η1-1,2-bis(diphenylphosphino)ethane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 13939-06-5,199620-15-0
molybdenum hexacarbonyl

: 15444-66-3
(1,2-bis(diphenylphosphino)ethane)tetracarbonylmolybdenum

: 14489-09-9
Mo2(CO)10(μ-1,2-bis(diphenylphosphino)ethane)

: 52901-70-9
Mo(CO)5(η1-1,2-bis(diphenylphosphino)ethane)

Guidance literature:: With trimethylamine-N-oxide; In tetrahydrofuran; acetonitrile; stirring Mo(CO)6 in MeCN with Me3NO*2H2O in vacuo under Ar, dropwise addn. of soln. into a continuously stirred soln. of ligand in MeCN/THF via a teflon transfer tube, stirring for 45 min at room temp. under Ar; reducing by half and stirring for another 35 min, pptn., filtn., recrystn. from CH2Cl2/MeOH, evapn. of filtrate to dryness in vacuo, dissolution (CH2Cl2), chromy., elution (CH2Cl2/n-hexane), extn. (CH2Cl2), recrystn. (CH2Cl2/MeOH), elem. anal.;
DOI:10.1016/0022-328X(93)83146-M

Reference yield: 32.0%

: 14040-11-0
tungsten hexacarbonyl

: 52901-70-9
Mo(CO)5(η1-1,2-bis(diphenylphosphino)ethane)

: 152223-53-5
(CO)5Mo(μ-1,3-bis(diphenylphosphino)propane)W(CO)5

Guidance literature:: With trimethylamine-N-oxide; In tetrahydrofuran; stirring W(CO)6 with Me3NO*2H2O in THF in vacuo for 20 min under Ar, filtn. into a flask containing a THF soln. of Mo-complex via a teflon transfer tube, stirring for 17 h at room temp. under Ar; removal of solvent in vacuo, extn. with a minimum amount of CH2Cl2, chromy. on silica (tlc plates), elution with CH2Cl2/hexane, recrystn. from CH2Cl2/MeOH, elem. anal.;
DOI:10.1016/0022-328X(93)83146-M

Reference yield: 15.6%

: 14040-11-0
tungsten hexacarbonyl

: 52901-70-9
Mo(CO)5(η1-1,2-bis(diphenylphosphino)ethane)

: 75365-60-5
(CO)5Mo(μ-1,2-bis(diphenylphosphino)ethane)W(CO)5

Guidance literature:: With trimethylamine-N-oxide; In tetrahydrofuran; stirring W(CO)6 with Me3NO*2H2O in THF in vacuo for 20 min under Ar, filtn. into a flask containing a THF soln. of Mo-complex via a teflon transfer tube, stirring for 17 h at room temp. under Ar; removal of solvent in vacuo, extn. with a minimum amount of CH2Cl2, chromy. on silica (tlc plates), elution with CH2Cl2/hexane, recrystn. from CH2Cl2/MeOH, elem. anal.;
DOI:10.1016/0022-328X(93)83146-M