tris(2,6-di-tert-butyl-4-methylphenolato-O)(triphenylphosphine oxide-O)samarium(III)

Base Information

• Chemical Name: tris(2,6-di-tert-butyl-4-methylphenolato-O)(triphenylphosphine oxide-O)samarium(III)
• CAS No.: 316188-52-0
• Molecular Formula: C₆₃H₈₄O₄PSm
• Molecular Weight: 1086.69
• Mol file: 316188-52-0.mol

Synonyms:

Chemical Property of tris(2,6-di-tert-butyl-4-methylphenolato-O)(triphenylphosphine oxide-O)samarium(III)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of tris(2,6-di-tert-butyl-4-methylphenolato-O)(triphenylphosphine oxide-O)samarium(III)

There total 1 articles about tris(2,6-di-tert-butyl-4-methylphenolato-O)(triphenylphosphine oxide-O)samarium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

((C6H2-tBu2-2,6-Me-4)O)2Sm(II)(tetrahydrofuran)3 complex (159404-04-3,166943-02-8,163059-98-1,158759-39-8) + Triphenylphosphine oxide (791-28-6) → tris(2,6-di-tert-butyl-4-methylphenolato-O)(triphenylphosphine oxide-O)samarium(III) (316188-52-0)

Guidance literature:

In toluene; Ar, Schlenk technique; Sm complex and excess of triphenylphoshine oxide in ethanol heated at 353 K; crystd. from toluene at 263 K;

DOI:10.1107/S0108270100010192

upstream raw materials:

((C₆H₂-tBu₂-2,6-Me-4)O)2Sm(II)(tetrahydrofuran)3 complex

Triphenylphosphine oxide