Phosphoric acid dibenzyl ester (1S,2R,3R,4S,5R,6S)-3-(bis-benzyloxy-phosphoryloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4,6-tris-methoxymethoxy-cyclohexyl ester

Base Information

Chemical Name:Phosphoric acid dibenzyl ester (1S,2R,3R,4S,5R,6S)-3-(bis-benzyloxy-phosphoryloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4,6-tris-methoxymethoxy-cyclohexyl ester
CAS No.:496808-71-0
Molecular Formula:C₅₆H₆₈O₁₅P₂Si
Molecular Weight:1071.18
Hs Code.:

Phosphoric acid dibenzyl ester (1S,2R,3R,4S,5R,6S)-3-(bis-benzyloxy-phosphoryloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4,6-tris-methoxymethoxy-cyclohexyl ester

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Chemical Property of Phosphoric acid dibenzyl ester (1S,2R,3R,4S,5R,6S)-3-(bis-benzyloxy-phosphoryloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4,6-tris-methoxymethoxy-cyclohexyl ester

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Technology Process of Phosphoric acid dibenzyl ester (1S,2R,3R,4S,5R,6S)-3-(bis-benzyloxy-phosphoryloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4,6-tris-methoxymethoxy-cyclohexyl ester

There total 7 articles about Phosphoric acid dibenzyl ester (1S,2R,3R,4S,5R,6S)-3-(bis-benzyloxy-phosphoryloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4,6-tris-methoxymethoxy-cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: Phosphorous acid dibenzyl ester (1S,2R,3R,4S,5R,6S)-3-(bis-benzyloxy-phosphanyloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4,6-tris-methoxymethoxy-cyclohexyl ester

: 496808-71-0
Phosphoric acid dibenzyl ester (1S,2R,3R,4S,5R,6S)-3-(bis-benzyloxy-phosphoryloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4,6-tris-methoxymethoxy-cyclohexyl ester

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; at -30 ℃;
DOI:10.1021/jo0206418

Reference yield:

: 331679-26-6
2,3-O-(D-1,7,7-trimethylbicyclo[2.2.1]hept-6-ylidene)-D-myo-inositol

: 496808-71-0
Phosphoric acid dibenzyl ester (1S,2R,3R,4S,5R,6S)-3-(bis-benzyloxy-phosphoryloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4,6-tris-methoxymethoxy-cyclohexyl ester

Guidance literature:: Multi-step reaction with 6 steps

1.1: 88 percent / imidazole

2.1: 90 percent / HSCH₂CH₂OH; BF₃*Et₂O

3.1: pyridine / CH₂Cl₂ / 1 h / -50 °C

3.2: diisopropylethylamine

3.3: 31 percent / methylamine / methanol / 48 h / 20 °C

4.1: 85 percent / sodium methoxide / methanol / 3 h

5.1: tetrazole

6.1: 3-chloroperoxybenzoic acid / -30 °C

With pyridine; 1H-imidazole; 1H-tetrazole; boron trifluoride diethyl etherate; sodium methylate; 3-chloro-benzenecarboperoxoic acid; 2-hydroxyethanethiol; In methanol; dichloromethane;
DOI:10.1021/jo0206418

Reference yield:

: 142534-54-1
1D-1-O-(tert-butyldiphenylsilyl)-myo-inositol

: 496808-71-0
Phosphoric acid dibenzyl ester (1S,2R,3R,4S,5R,6S)-3-(bis-benzyloxy-phosphoryloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4,6-tris-methoxymethoxy-cyclohexyl ester

Guidance literature:: Multi-step reaction with 4 steps

1.1: pyridine / CH₂Cl₂ / 1 h / -50 °C

1.2: diisopropylethylamine

1.3: 31 percent / methylamine / methanol / 48 h / 20 °C

2.1: 85 percent / sodium methoxide / methanol / 3 h

3.1: tetrazole

4.1: 3-chloroperoxybenzoic acid / -30 °C

With pyridine; 1H-tetrazole; sodium methylate; 3-chloro-benzenecarboperoxoic acid; In methanol; dichloromethane;
DOI:10.1021/jo0206418