Acetic acid ((4S,5S,4'S,5'S)-5'-benzhydryloxymethyl-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-phenylsulfanyl-methyl ester

Base Information

Chemical Name:Acetic acid ((4S,5S,4'S,5'S)-5'-benzhydryloxymethyl-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-phenylsulfanyl-methyl ester
CAS No.:128990-44-3
Molecular Formula:C₃₃H₃₈O₇S
Molecular Weight:578.727
Hs Code.:

Synonyms:

Suppliers and Price of Acetic acid ((4S,5S,4'S,5'S)-5'-benzhydryloxymethyl-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-phenylsulfanyl-methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Acetic acid ((4S,5S,4'S,5'S)-5'-benzhydryloxymethyl-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-phenylsulfanyl-methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Acetic acid ((4S,5S,4'S,5'S)-5'-benzhydryloxymethyl-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-phenylsulfanyl-methyl ester

There total 64 articles about Acetic acid ((4S,5S,4'S,5'S)-5'-benzhydryloxymethyl-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-phenylsulfanyl-methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 128990-38-5,128990-39-6,129097-75-2,129097-78-5,129097-79-6,129097-80-9,129099-48-5,129099-49-6
(4R,5R,4'S,5'S)-5-Benzenesulfinylmethyl-5'-benzhydryloxymethyl-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]

: 108-24-7
acetic anhydride

: 128990-44-3,128990-47-6,128990-48-7,128990-53-4,129006-12-8,129006-13-9,129006-14-0,129006-15-1
Acetic acid ((4R,5R,4'S,5'S)-5'-benzhydryloxymethyl-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-phenylsulfanyl-methyl ester

Guidance literature:: With sodium acetate; Heating;
DOI:10.1016/S0040-4020(01)97596-9

Reference yield:

: 128990-34-1
(E)-4-(benzhydryloxy)but-2-enal

: 128990-44-3,128990-47-6,128990-48-7,128990-53-4,129006-12-8,129006-13-9,129006-14-0,129006-15-1
Acetic acid ((4R,5R,4'R,5'S)-5'-benzhydryloxymethyl-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-phenylsulfanyl-methyl ester

Guidance literature:: Multi-step reaction with 14 steps

1: 100 percent / NaBH₄ / methanol / 3 h / -20 - -10 °C

2: 92 percent / t-BuOCl, L-(+)-diisopropyl tartrate*Ti(OiPr)4 / CH₂Cl₂ / -20 °C

3: 71 percent / 0.5N NaOH / 2-methyl-propan-2-ol / Heating

4: POCl₃ / CH₂Cl₂ / Ambient temperature

5: m-chloroperoxybenzoic acid / CH₂Cl₂ / -78 °C

6: NaOAc / 8 h / Heating

7: 100 percent / K₂CO₃ / methanol / Ambient temperature

8: 91 percent / benzene / Ambient temperature

9: NaBH₄ / methanol / -20 - -10 °C

10: 73 percent / t-BuOCl, D-(-)-diisopropyl tartrate, Ti(OiPr)4 / CH₂Cl₂ / -20 °C

11: 0.5N NaOH / 2-methyl-propan-2-ol / Heating

12: d-10-Camphersulfonic acid / CH₂Cl₂ / Ambient temperature

13: m-chloroperoxybenzoic acid / CH₂Cl₂ / -78 °C

14: NaOAc / Heating

With titanium(IV) isopropylate; sodium hydroxide; sodium tetrahydroborate; tert-butylhypochlorite; L-(+)-diisopropyl tartrate*Ti(OiPr)4; sodium acetate; potassium carbonate; D-(-)-diisopropyl tartrate; (+)-10-camphorsulfonic acid; 3-chloro-benzenecarboperoxoic acid; trichlorophosphate; In methanol; dichloromethane; tert-butyl alcohol; benzene;
DOI:10.1016/S0040-4020(01)97596-9

Reference yield:

: 128990-34-1
(E)-4-(benzhydryloxy)but-2-enal

: 128990-44-3,128990-47-6,128990-48-7,128990-53-4,129006-12-8,129006-13-9,129006-14-0,129006-15-1
Acetic acid ((4R,5R,4'S,5'S)-5'-benzhydryloxymethyl-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-phenylsulfanyl-methyl ester

Guidance literature:: Multi-step reaction with 14 steps

1: 100 percent / NaBH₄ / methanol / 3 h / -20 - -10 °C

2: 92 percent / t-BuOCl, L-(+)-diisopropyl tartrate*Ti(OiPr)4 / CH₂Cl₂ / -20 °C

3: 71 percent / 0.5N NaOH / 2-methyl-propan-2-ol / Heating

4: POCl₃ / CH₂Cl₂ / Ambient temperature

5: m-chloroperoxybenzoic acid / CH₂Cl₂ / -78 °C

6: NaOAc / 8 h / Heating

7: 91 percent / diisobutylaluminum hydride / CH₂Cl₂; hexane / 0.5 h / -78 °C

8: 88 percent / benzene / Ambient temperature

9: 91 percent / NaBH₄ / methanol / -20 - -10 °C

10: 84 percent / t-BuOCl, D-(-)-diisopropyl tartrate, Ti(OiPr)4 / CH₂Cl₂ / -20 °C

11: 63 percent / 0.5N NaOH / 2-methyl-propan-2-ol / Heating

12: 100 percent / d-10-Camphersulfonic acid / CH₂Cl₂ / 0.5 h / Ambient temperature

13: 97 percent / m-chloroperoxybenzoic acid / CH₂Cl₂ / -78 °C

14: 90 percent / NaOAc / Heating

With titanium(IV) isopropylate; sodium hydroxide; sodium tetrahydroborate; tert-butylhypochlorite; L-(+)-diisopropyl tartrate*Ti(OiPr)4; sodium acetate; diisobutylaluminium hydride; D-(-)-diisopropyl tartrate; (+)-10-camphorsulfonic acid; 3-chloro-benzenecarboperoxoic acid; trichlorophosphate; In methanol; hexane; dichloromethane; tert-butyl alcohol; benzene;
DOI:10.1016/S0040-4020(01)97596-9