1-chlorodimethylstannyl-2-methyl(phenyl)borylferrocene

Base Information

Chemical Name:1-chlorodimethylstannyl-2-methyl(phenyl)borylferrocene
CAS No.:223114-84-9
Molecular Formula:C₁₉H₂₂BClFeSn
Molecular Weight:471.205
Hs Code.:

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Chemical Property of 1-chlorodimethylstannyl-2-methyl(phenyl)borylferrocene

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Technology Process of 1-chlorodimethylstannyl-2-methyl(phenyl)borylferrocene

There total 4 articles about 1-chlorodimethylstannyl-2-methyl(phenyl)borylferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

: 70595-34-5
1,1'-bis(trimethylstannyl)ferrocene

: 873-51-8
phenylborondichloride

: 223114-84-9
1-chlorodimethylstannyl-2-methyl(phenyl)borylferrocene

Guidance literature:: In hexane; a soln. of C6H5BCl2 in hexane was added dropwise to a soln. of complex in hexane at -78°C, the mixt. was allowed to warm to ambient temp.and stirred for 12 h (N2); volatiles were removed under reduced pressure (1E-3 Torr), kept under dynamic vac. at 80°C over 5 h, dissolved in hexane, filtered, recrystd. at -37°C from hexane;
DOI:10.1021/om0204890

Reference yield:

: [K(18-rown-6)][1,2-ferrocenediyl(BMePh))(SnMe₂Cl)F]

: 223114-84-9
1-chlorodimethylstannyl-2-methyl(phenyl)borylferrocene

Guidance literature:: With Me₂SnCl₂; In tetrahydrofuran; (N2); Schlenk technique or glovebox; soln. of Fe-K complex in THF was added with stirring to soln. of Me2SnCl2 in THF; stirred at room temp. for30 min; volatiles removed (vac.); extd. (hexane); solvent removed;
DOI:10.1021/om700967a