(η4-cyclooctadiene)[1-(4,5-dihydro-4,4-dimethyloxazol-2-yl)-3-mesitylimidazol-2-ylidene]rhodium(I) hexafluorophosphate

Base Information

• Chemical Name: (η4-cyclooctadiene)[1-(4,5-dihydro-4,4-dimethyloxazol-2-yl)-3-mesitylimidazol-2-ylidene]rhodium(I) hexafluorophosphate
• CAS No.: 821772-61-6
• Molecular Formula: C₂₅H₃₃N₃ORh*F₆P
• Molecular Weight: 639.426
• Mol file: 821772-61-6.mol

Synonyms:

Chemical Property of (η4-cyclooctadiene)[1-(4,5-dihydro-4,4-dimethyloxazol-2-yl)-3-mesitylimidazol-2-ylidene]rhodium(I) hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η4-cyclooctadiene)[1-(4,5-dihydro-4,4-dimethyloxazol-2-yl)-3-mesitylimidazol-2-ylidene]rhodium(I) hexafluorophosphate

There total 1 articles about (η4-cyclooctadiene)[1-(4,5-dihydro-4,4-dimethyloxazol-2-yl)-3-mesitylimidazol-2-ylidene]rhodium(I) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

potassium hexafluorophosphate (17084-13-8) + bromo(η4-cyclooctadiene)[1-(4,5-dihydro-4,4-dimethyloxazol-2-yl)-3-mesitylimidazol-2-ylidene]rhodium(I) (821772-58-1) → (η4-cyclooctadiene)[1-(4,5-dihydro-4,4-dimethyloxazol-2-yl)-3-mesitylimidazol-2-ylidene]rhodium(I) hexafluorophosphate (821772-61-6)

Guidance literature:

In dichloromethane; water; under N2, Schlenk setup; solid KPF6 (1.5 equiv.) added to soln. of Rh complex in CH2Cl2, degassed water added, stirred vigorously for 30 min; org. layer decanted, aq. phase washed with CH2Cl2, combined org. layers dried over Na2SO4, filtered, filtrate evapd., residue washed with Et2O, dried under vac.; elem. anal.;

DOI:10.1002/ejic.200400182

upstream raw materials:

potassium hexafluorophosphate

bromo(η4-cyclooctadiene)[1-(4,5-dihydro-4,4-dimethyloxazol-2-yl)-3-mesitylimidazol-2-ylidene]rhodium(I)