[RuHCl(Sb(CH₂Ph)3)(PCy₃)2]

Base Information

• Chemical Name: [RuHCl(Sb(CH₂Ph)3)(PCy₃)2]
• CAS No.: 691879-52-4
• Molecular Formula: C₅₇H₈₈ClP₂RuSb
• Molecular Weight: 1093.55
• Mol file: 691879-52-4.mol

Synonyms:

Chemical Property of [RuHCl(Sb(CH₂Ph)3)(PCy₃)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [RuHCl(Sb(CH₂Ph)3)(PCy₃)2]

There total 1 articles about [RuHCl(Sb(CH₂Ph)3)(PCy₃)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

[RuHCl(H2)(PCy3)2] (315675-18-4,133779-04-1) + tribenzylstibane (5072-92-4) → [RuHCl(Sb(CH2Ph)3)(PCy3)2] (691879-52-4)

Guidance literature:

In dichloromethane; byproducts: H2; under Ar; a soln. of Ru-contg. compd. (0.10 mmol) in CH2Cl2 was treated with Sb-contg. compd. (0.10 mmol) and stirred for 45 min at room temp.; slow evolution of gas was observed; the solvent was evapd. in vac.; the solid was washed with pentane and dried; elem. anal.;

DOI:10.1039/b314425a

Reference yield: 99.0%

[RuHCl(Sb(CH2Ph)3)(PCy3)2] (691879-52-4) + acetylene (74-86-2,25067-58-7) → [hydridobis(tricyclohexylphosphane)(vinyldene)chlororuthenium(II)] + [RuCl(CH=CH2)(Sb(CH2Ph)3)(PCy3)2] + tribenzylstibane (5072-92-4)

Guidance literature:

In dichloromethane; under Ar; a slow stream of acetylene was passed at -78°C through a soln. of Ru-contg. compd. (0.04 mmol) in CH2Cl2 for 30 s; a gradual change of colour from brown-yellow to red-brown was observed; the solvent was evapd. in vac.; detd. by (1)H and (31)P NMR spectra studies;

DOI:10.1039/b314425a

Reference yield: 99.0%

[RuHCl(Sb(CH2Ph)3)(PCy3)2] (691879-52-4) + phenylacetylene (536-74-3) → [hydridobis(tricyclohexylphosphane)(phenylethylene)chlororuthenium(II)] + [RuCl(CH=CHPh)(Sb(CH2Ph)3)(PCy3)2] + tribenzylstibane (5072-92-4)

Guidance literature:

In dichloromethane-d2; under Ar; in a NMR tube, a soln. of Ru-contg. compd. (0.04 mmol) in CD2Cl2 was treated with phenylacetylene (0.05 mmol); detd. by (1)H and (31)P NMR spectra studies;

DOI:10.1039/b314425a

upstream raw materials:

[RuHCl(H₂)(PCy₃)2]

tribenzylstibane

Downstream raw materials:

tribenzylstibane

Refernces