[PtPdCl₄((C₆H₅)2PCCP(C₆H₅)2)2]*2CHCl₃

Base Information

• Chemical Name: [PtPdCl₄((C₆H₅)2PCCP(C₆H₅)2)2]*2CHCl₃
• CAS No.: 98087-77-5
• Molecular Formula: 2CHCl₃*C₅₂H₄₀Cl₄P₄PdPt
• Molecular Weight: 1470.85
• Mol file: 98087-77-5.mol

Synonyms:

Chemical Property of [PtPdCl₄((C₆H₅)2PCCP(C₆H₅)2)2]*2CHCl₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PtPdCl₄((C₆H₅)2PCCP(C₆H₅)2)2]*2CHCl₃

There total 2 articles about [PtPdCl₄((C₆H₅)2PCCP(C₆H₅)2)2]*2CHCl₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cis-[bis(dimethylphenylphosphane)dichlroplatinum(II)] (15393-14-3) → trans-dichlorobis(dimethylphenylphosphine)palladium(II) (29484-66-0,15616-85-0,29484-74-0) + [PtPdCl4((C6H5)2PCCP(C6H5)2)2]*2CHCl3 (98087-77-5)

Guidance literature:

Multi-step reaction with 2 steps

1: xylene

2: CHCl₃ / benzene

With CHCl₃; In benzene;

Reference yield:

{(PPhMe2)ClPd(μ-Cl)2PtCl(PPhMe2)} (95387-54-5) + bis(diphenylphosphino)acetylene (5112-95-8) → cis-[bis(dimethylphenylphosphane)dichlroplatinum(II)] (15393-14-3) + trans-dichlorobis(dimethylphenylphosphine)palladium(II) (29484-66-0,15616-85-0,29484-74-0) + [PtPdCl4((C6H5)2PCCP(C6H5)2)2]*2CHCl3 (98087-77-5)

Guidance literature:

With CHCl₃; In benzene; slow addn. of 0.10g diphosphine in 10ml C6H6 to a soln. of 0.20g Pt-Pd-complex in 20ml C6H6, pptn., stirring for 2h, filtration;; dissolving residue in CHCl3, crystn. on slow evapn. of solvent; elem. anal.; cis-(PtCl2(PMe2Ph)2) and trans-(PdCl2(PMe2Ph)2) were detected in the filtrate by NMR spectroscopy;;

Reference yield:

[PtPdCl4((C6H5)2PCCP(C6H5)2)2]*2CHCl3 (98087-77-5) → [Pt2Cl4(1,2-bis(diphenylphosphanyl)acetylene)2] (190021-72-8,21108-38-3) + [Pd2Cl4((C6H5)2PC2P(C6H5)2)2] (21108-42-9)

Guidance literature:

In dichloromethane; equilibrium in soln.;; not isolated; detected by (31)P- and (195)Pt-NMR;;

upstream raw materials:

{(PPhMe2)ClPd(μ-Cl)2PtCl(PPhMe2)}

bis(diphenylphosphino)acetylene

cis-[bis(dimethylphenylphosphane)dichlroplatinum(II)]

Downstream raw materials:

[Pt₂Cl₄(1,2-bis(diphenylphosphanyl)acetylene)₂]

[Pd₂Cl₄((C₆H₅)2PC₂P(C₆H₅)2)2]