Chloro-acetic acid (2R,3R,4S,5R,6R)-3-acetoxy-4,5-bis-benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-chloro-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-2-ylmethyl ester

Base Information

Chemical Name:Chloro-acetic acid (2R,3R,4S,5R,6R)-3-acetoxy-4,5-bis-benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-chloro-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-2-ylmethyl ester
CAS No.:115435-51-3
Molecular Formula:C₅₁H₅₄Cl₂O₁₂
Molecular Weight:929.889
Hs Code.:

Chloro-acetic acid (2R,3R,4S,5R,6R)-3-acetoxy-4,5-bis-benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-chloro-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-2-ylmethyl ester

Synonyms:

Suppliers and Price of Chloro-acetic acid (2R,3R,4S,5R,6R)-3-acetoxy-4,5-bis-benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-chloro-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-2-ylmethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Chloro-acetic acid (2R,3R,4S,5R,6R)-3-acetoxy-4,5-bis-benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-chloro-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-2-ylmethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Chloro-acetic acid (2R,3R,4S,5R,6R)-3-acetoxy-4,5-bis-benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-chloro-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-2-ylmethyl ester

There total 3 articles about Chloro-acetic acid (2R,3R,4S,5R,6R)-3-acetoxy-4,5-bis-benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-chloro-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-2-ylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: O-(4-O-acetyl-2,3-di-O-benzyl-6-O-monochloroacetyl-α-D-glucopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-D-glucopyranose

: 115435-51-3
Chloro-acetic acid (2R,3R,4S,5R,6R)-3-acetoxy-4,5-bis-benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-chloro-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-2-ylmethyl ester

Guidance literature:: With thionyl chloride; In 1,2-dichloro-ethane; N,N-dimethyl-formamide; at 20 ℃; for 19h;
DOI:10.1016/0008-6215(87)80246-X

Reference yield:

: 115435-47-7
allyl O-(2,3-di-O-benzyl-6-O-monochloroacetyl-α-D-glucopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

: 115435-51-3
Chloro-acetic acid (2R,3R,4S,5R,6R)-3-acetoxy-4,5-bis-benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-chloro-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-2-ylmethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / pyridine / 4 h / 20 °C

2: 86 percent / PdCl₂, NaOAc / acetic acid; H₂O / 2 h / 50 °C

3: SOCl₂ / 1,2-dichloro-ethane; dimethylformamide / 19 h / 20 °C

With pyridine; thionyl chloride; sodium acetate; palladium dichloride; In water; acetic acid; 1,2-dichloro-ethane; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(87)80246-X

Reference yield:

: 115435-49-9
allyl O-(4-O-acetyl-2,3-di-O-benzyl-6-O-monochloroacetyl-α-D-glucopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

: 115435-51-3
Chloro-acetic acid (2R,3R,4S,5R,6R)-3-acetoxy-4,5-bis-benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-chloro-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-2-ylmethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 86 percent / PdCl₂, NaOAc / acetic acid; H₂O / 2 h / 50 °C

2: SOCl₂ / 1,2-dichloro-ethane; dimethylformamide / 19 h / 20 °C

With thionyl chloride; sodium acetate; palladium dichloride; In water; acetic acid; 1,2-dichloro-ethane; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(87)80246-X