Technology Process of C33H46O7Si
There total 14 articles about C33H46O7Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C23H24O5;
With
(-)-diisopinocampheyl chloride; triethylamine;
In
diethyl ether;
at -78 - 0 ℃;
for 1h;
(S)-3-(tert-butyldimethylsilyloxy)butanal;
In
diethyl ether;
at -78 ℃;
for 2h;
Overall yield = 43 %; Overall yield = 10 mg;
DOI:10.1021/ol303482k
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: lithium chloride / tetrahydrofuran; diethyl ether / 0.5 h / -78 °C
2.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 3 h / 20 °C
3.1: (-)-diisopinocampheyl chloride; triethylamine / diethyl ether / 1 h / -78 - 0 °C
3.2: 2 h / -78 °C
With
(-)-diisopinocampheyl chloride; triethylamine; lithium chloride; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;
In
tetrahydrofuran; diethyl ether; dimethyl sulfoxide;
DOI:10.1021/ol303482k
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 3 h / 20 °C
2.1: (-)-diisopinocampheyl chloride; triethylamine / diethyl ether / 1 h / -78 - 0 °C
2.2: 2 h / -78 °C
With
(-)-diisopinocampheyl chloride; triethylamine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;
In
diethyl ether; dimethyl sulfoxide;
DOI:10.1021/ol303482k
