tetrakis(p-tolyl)oxalamidinato-bis[acetylacetonatopalladium(II)]

Base Information

Chemical Name:tetrakis(p-tolyl)oxalamidinato-bis[acetylacetonatopalladium(II)]
CAS No.:365540-76-7
Molecular Formula:C₄₀H₄₂N₄O₄Pd₂
Molecular Weight:855.638
Hs Code.:

Synonyms:

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Chemical Property of tetrakis(p-tolyl)oxalamidinato-bis[acetylacetonatopalladium(II)]

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Technology Process of tetrakis(p-tolyl)oxalamidinato-bis[acetylacetonatopalladium(II)]

There total 1 articles about tetrakis(p-tolyl)oxalamidinato-bis[acetylacetonatopalladium(II)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: bis(acetylacetonato)palladium(II)

: 75390-40-8
N⁽¹⁾,N⁽²⁾,N⁽³⁾,N⁽⁴⁾-tetra(p-tolyl)oxalamidine

: 365540-76-7
tetrakis(p-tolyl)oxalamidinato-bis[acetylacetonatopalladium(II)]

Guidance literature:: In toluene; byproducts: acetylacetone; all manipulations under Ar atm.; N and Pd compds. suspended in toluene, refluxed for 3 h; solvent removed, filtered, washed with toluene and Et2O, recrystd. from hot benyene, elem. anal.;
DOI:10.1002/1099-0682(200108)2001:8<2049::AID-EJIC2049>3.0.CO;2-J

Reference yield: 70.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 4440-01-1
lithium phenylacetylide

: 365540-76-7
tetrakis(p-tolyl)oxalamidinato-bis[acetylacetonatopalladium(II)]

: 917-54-4
methyllithium

: [Pd(CH₃)(CCC₆H₅)3Li₂(thf)4]

Guidance literature:: In tetrahydrofuran; diethyl ether; (Ar); Schlenk techniques; THS suspn. of Pd(II) deriv. added to THF soln.of phenyethynyllithium, both at -78°C; MeLi/Et2O added dropwise; warmed slowly to room temp.; filtered; partial evapn.; pptd. by addn. of toluene and subsequent cooling to -25°C; dried in vac.;
DOI:10.1002/zaac.200801196

Reference yield: 60.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 365540-76-7
tetrakis(p-tolyl)oxalamidinato-bis[acetylacetonatopalladium(II)]

: 917-54-4
methyllithium

: 536-74-3
phenylacetylene

: [Pd₂(CH₃)4(CCC₆H₅)4Li₄(thf)6]

Guidance literature:: In tetrahydrofuran; diethyl ether; (Ar); Schlenk techniques; Et2O soln. of MeLi added dropwise to THF soln.of phenylacetylene at -78°C; warmed to room temp.; cooled to -78 °C; THF suspn. of Pd(II) deriv. added; slowly warmed to room temp.; evapn.; redissolved in Et2O; filtered; partial evapn.; pptd. by cooling to -25°C; decanted; washed with pentane; vac. dried;
DOI:10.1002/zaac.200801196