1,3a,6,8a-Tetrahydro-1,6-ethenoazulene

Base Information

Chemical Name:1,3a,6,8a-Tetrahydro-1,6-ethenoazulene
CAS No.:15991-78-3
Molecular Formula:C₁₂H₁₂
Molecular Weight:156.227
Hs Code.:
Mol file:15991-78-3.mol

Synonyms:

Suppliers and Price of 1,3a,6,8a-Tetrahydro-1,6-ethenoazulene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 1,3a,6,8a-Tetrahydro-1,6-ethenoazulene

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,3a,6,8a-Tetrahydro-1,6-ethenoazulene

There total 6 articles about 1,3a,6,8a-Tetrahydro-1,6-ethenoazulene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₉H₂₀N₂O₂S

: 15991-78-3
Tricyclo<5.3.2.0^4,8>dodeca-2,5,9,11-tetraen

Guidance literature:: With n-butyllithium; In tetrahydrofuran; at -78 - 25 ℃;
DOI:10.1016/j.tetlet.2017.12.042

Reference yield:

: C₁₂H₁₂

: 15991-78-3
Tricyclo<5.3.2.0^4,8>dodeca-2,5,9,11-tetraen

Guidance literature:: With silver perchlorate; In chloroform; at 20 ℃; Darkness;
DOI:10.1016/j.tetlet.2017.12.042

Reference yield:

: 1005-51-2
bullvalene

: 15991-78-3
Tricyclo<5.3.2.0^4,8>dodeca-2,5,9,11-tetraen

Guidance literature:: Multi-step reaction with 5 steps

1: trichlorophosphate

2: zinc(II) chloride

3: zinc; ammonium chloride / methanol / Reflux

4: toluene-4-sulfonic acid

5: n-butyllithium / tetrahydrofuran / -78 - 25 °C

With n-butyllithium; ammonium chloride; toluene-4-sulfonic acid; zinc(II) chloride; zinc; trichlorophosphate; In tetrahydrofuran; methanol; 5: |Shapiro Olefination;
DOI:10.1016/j.tetlet.2017.12.042