[Pd(η3-2-CH3-C3H4)(2-pyridyldiphenylphosphine)2](BF4)

Base Information

• Chemical Name: [Pd(η3-2-CH3-C3H4)(2-pyridyldiphenylphosphine)2](BF4)
• CAS No.: 947383-37-1
• Molecular Formula: BF₄*C₃₈H₃₅N₂P₂Pd
• Molecular Weight: 774.881
• Mol file: 947383-37-1.mol

Synonyms:

Chemical Property of [Pd(η3-2-CH3-C3H4)(2-pyridyldiphenylphosphine)2](BF4)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [Pd(η3-2-CH3-C3H4)(2-pyridyldiphenylphosphine)2](BF4)

There total 1 articles about [Pd(η3-2-CH3-C3H4)(2-pyridyldiphenylphosphine)2](BF4) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

2-(diphenylphosphino)pyridine (37943-90-1) + Pd2(η3-2-CH3C3H4)2(μ-PPh2py)2(BF4)2 → [Pd(η3-2-CH3-C3H4)(2-pyridyldiphenylphosphine)2](BF4) (947383-37-1)

Guidance literature:

In dichloromethane; (under Ar, Schlenk); soln. of ligand in CH2Cl2 added to soln. of Pd-complex in CH2Cl2, stirred for 1 h at room temp.; concd. under reduced pressure, Et2O added; elem. anal.;

DOI:10.1016/j.jorganchem.2007.04.021

Reference yield: 75.0%

[Pd(η3-2-CH3-C3H4)(2-pyridyldiphenylphosphine)2](BF4) (947383-37-1) + 1,2-Dicyanoethylene (764-42-1) → [Pd(η2-fumaronitrile)(2-pyridyldiphenylphosphine)2]

Guidance literature:

With diethylamine; In dichloromethane; (Ar); std. Schlenk technique; nitrile was added to soln. of Pd complex in CH2Cl2; soln. of Et2N in CH2Cl2 was added; stirred for 1 h; extd. (H2O); dried (MgSO4); filtered; concd. (vac.); hexane added; elem.anal.;

DOI:10.1016/j.jorganchem.2008.09.063

Reference yield:

methanesulfonic acid (75-75-2,98527-29-8) + [Pd(η3-2-CH3-C3H4)(2-pyridyldiphenylphosphine)2](BF4) (947383-37-1) → [Pd(η3-2-CH3-C3H4)(2-pyridyldiphenylphosphine(+1H))2](BF4)(CH3SO3)2

Guidance literature:

In dichloromethane-d2; (Ar); std. Schlenk technique; acid (2 equiv.) was added to soln. of Pd complex in CD2Cl2; NMR monitoring;

DOI:10.1016/j.jorganchem.2008.09.063

upstream raw materials:

2-(diphenylphosphino)pyridine