dibenzotetraphenyltetraazaporphyrin copper complex

Base Information

• Chemical Name: dibenzotetraphenyltetraazaporphyrin copper complex
• CAS No.: 243459-67-8
• Molecular Formula: C₄₈H₂₈CuN₈
• Molecular Weight: 780.35
• Mol file: 243459-67-8.mol

Synonyms:

Chemical Property of dibenzotetraphenyltetraazaporphyrin copper complex

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dibenzotetraphenyltetraazaporphyrin copper complex

There total 2 articles about dibenzotetraphenyltetraazaporphyrin copper complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.0%

Ph2(NH2)(C4N)N(C8H4N)NH (243459-79-2) + copper(l) chloride → dibenzotetraphenyltetraazaporphyrin copper complex (243459-67-8) + dibenzotetraphenyltetraazaporphyrin copper complex (243459-53-2)

Guidance literature:

With sodium methylate; hydroquinone; In acetone; Russ. J. Gen. Chem., 1999, vol. 69, no. 2, p. 314; cyclization in boiling acetone in the presence of hydroquinone and CH3ONa and CuCl; extd.; column chromy.; TLC (silufol, benzene-heptane 9:1);

DOI:10.1007/s11176-005-0101-9

Reference yield:

copper dichloride + 5-amino-2-imino-3,4-diphenyl-2H-pyrrole (35114-54-6) + 3-amino-1,1-dichloro-1H-isoindole hydrochloride → copper dibenzotetraphenyltetraazaporphine (243459-53-2) + copper dibenzotetraphenyltetraazaporphine (243459-67-8)

Guidance literature:

With sodium methylate; triethylamine; hydroquinone; In acetone; byproducts: triethylammonium hydrochloride; pyrrole soln. addn. dropwise to suspension of isoindole, stirring (1 h, room temperature), amine addn., ppt. filtration off, CuCl2 addn. to filtrate, stirring (room temperature, 1 h), Na-methylate and hydroquinone addn., refluxing (acetone, 56°C); column chromy. (silica gel, benzene-ethanol), heating (0.001 Pa, 200-250°C, 2 h); elem. anal., isomers not separated;

upstream raw materials:

5-amino-2-imino-3,4-diphenyl-2H-pyrrole

Ph₂(NH₂)(C₄N)N(C₈H₄N)NH