Technology Process of C57H100O7Si4
There total 18 articles about C57H100O7Si4 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
trifluoroacetic acid;
In
benzene;
at 20 ℃;
for 72h;
optical yield given as %de;
stereoselective reaction;
DOI:10.1080/00397911.2010.516462
- Guidance literature:
-
Multi-step reaction with 8 steps
1: acetic acid / water
2: 2,6-dimethylpyridine
3: hydrogenchloride / isopropyl alcohol / 6 h / 70 °C
4: oxalyl dichloride; dimethyl sulfoxide
5: lithium hexamethyldisilazane / 1 h / -78 °C
6: 2,6-dimethylpyridine
7: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 1 h / 20 °C
8: trifluoroacetic acid / benzene / 72 h / 20 °C
With
2,6-dimethylpyridine; hydrogenchloride; oxalyl dichloride; acetic acid; dimethyl sulfoxide; trifluoroacetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium hexamethyldisilazane;
In
dichloromethane; water; isopropyl alcohol; benzene;
4: Swern oxidation;
DOI:10.1080/00397911.2010.516462
- Guidance literature:
-
Multi-step reaction with 9 steps
1: toluene-4-sulfonic acid / tetrahydrofuran
2: acetic acid / water
3: 2,6-dimethylpyridine
4: hydrogenchloride / isopropyl alcohol / 6 h / 70 °C
5: oxalyl dichloride; dimethyl sulfoxide
6: lithium hexamethyldisilazane / 1 h / -78 °C
7: 2,6-dimethylpyridine
8: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 1 h / 20 °C
9: trifluoroacetic acid / benzene / 72 h / 20 °C
With
2,6-dimethylpyridine; hydrogenchloride; oxalyl dichloride; toluene-4-sulfonic acid; acetic acid; dimethyl sulfoxide; trifluoroacetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium hexamethyldisilazane;
In
tetrahydrofuran; dichloromethane; water; isopropyl alcohol; benzene;
5: Swern oxidation;
DOI:10.1080/00397911.2010.516462
