1,1‐diphenyl‐1,2,3,4‐tetrahydrosiline

Base Information

• Chemical Name: 1,1‐diphenyl‐1,2,3,4‐tetrahydrosiline
• CAS No.: 2736-08-5
• Molecular Formula: C₁₇H₁₈Si
• Molecular Weight: 250.415
• Mol file: 2736-08-5.mol

Synonyms:

Chemical Property of 1,1‐diphenyl‐1,2,3,4‐tetrahydrosiline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1‐diphenyl‐1,2,3,4‐tetrahydrosiline

There total 12 articles about 1,1‐diphenyl‐1,2,3,4‐tetrahydrosiline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

(5,5‐dichloropent‐4‐en‐1‐yl)diphenylsilane → 1,1‐diphenyl‐1,2,3,4‐tetrahydrosiline (2736-08-5)

Guidance literature:

With nickel(II) chloride ethylene glycol dimethyl ether complex; (±)-t-Bu-Quinox; zinc; In diethyl ether; N,N-dimethyl acetamide; at 20 ℃; for 16h; Reagent/catalyst; Solvent; Catalytic behavior; Inert atmosphere; Glovebox;

DOI:10.1039/d0cc05970f

Reference yield:

chloro-(5-chloro-pent-1-enyl)-diphenyl-silane (2736-25-6) → 1,1‐diphenyl‐1,2,3,4‐tetrahydrosiline (2736-08-5)

Guidance literature:

With sodium; In toluene;

DOI:10.1021/jo01019a017

Reference yield:

cis-und trans-5-Chlor-1-trichlorsilyl-1-penten (2736-07-4) → 1,1‐diphenyl‐1,2,3,4‐tetrahydrosiline (2736-08-5)

Guidance literature:

Multi-step reaction with 2 steps

2: Na / toluene

With sodium; In toluene;

DOI:10.1021/jo01019a017

upstream raw materials:

chloro-(5-chloro-pent-1-enyl)-diphenyl-silane

phenyllithium

1,1-dichloro-1,2,3,4-tetrahydro-siline

4-bromo-1,1-dichloro-1,2,3,4-tetrahydro-siline

Downstream raw materials:

1,1-diphenyl-silinan-2-ol

5-(hydroxy-diphenyl-silanyl)-pentanoic acid

2-methyl-1,1-diphenyl-silinan-2-ol

1,1-diphenyl-1-silacyclohexanone-2