3-(2'-nitrophenylthio)-tricyclo<2.2.1.0^2.6>heptane

Base Information

• Chemical Name: 3-(2'-nitrophenylthio)-tricyclo<2.2.1.0^2.6>heptane
• CAS No.: 74456-95-4
• Molecular Formula: C₁₃H₁₃NO₂S
• Molecular Weight: 247.318
• Mol file: 74456-95-4.mol

Synonyms:

Chemical Property of 3-(2'-nitrophenylthio)-tricyclo<2.2.1.0^2.6>heptane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-(2'-nitrophenylthio)-tricyclo<2.2.1.0^2.6>heptane

There total 8 articles about 3-(2'-nitrophenylthio)-tricyclo<2.2.1.0^2.6>heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C20H19N3O4S2 → 3-(2'-nitrophenylthio)-tricyclo<2.2.1.02.6>heptane (74456-95-4)

Guidance literature:

With methyllithium; lithium bromide; In diethyl ether; at 23 ℃; for 4h; Yield given;

Reference yield:

tetracyclo-[3.2.0.0.2,7.04,6]heptane (278-06-8) → 3-(2'-nitrophenylthio)-tricyclo<2.2.1.02.6>heptane (74456-95-4)

Guidance literature:

Multi-step reaction with 5 steps

1: acetic acid / 23 °C

2: sodium borohyidride, lithium chloride / propan-2-ol / 24 h / Heating

3: Jones' reagent / acetone / 25 °C

4: 78 percent / ethanol / 2 h / Heating

5: methyllithium, lithium bromide / diethyl ether / 4 h / 23 °C

With sodium tetrahydroborate; jones' reagent; methyllithium; lithium chloride; lithium bromide; In diethyl ether; ethanol; acetic acid; isopropyl alcohol; acetone;

Reference yield:

2-nitrobenzenesulfenyl chloride (7669-54-7) → 3-(2'-nitrophenylthio)-tricyclo<2.2.1.02.6>heptane (74456-95-4)

Guidance literature:

Multi-step reaction with 5 steps

1: acetic acid / 23 °C

2: sodium borohyidride, lithium chloride / propan-2-ol / 24 h / Heating

3: Jones' reagent / acetone / 25 °C

4: 78 percent / ethanol / 2 h / Heating

5: methyllithium, lithium bromide / diethyl ether / 4 h / 23 °C

With sodium tetrahydroborate; jones' reagent; methyllithium; lithium chloride; lithium bromide; In diethyl ether; ethanol; acetic acid; isopropyl alcohol; acetone;

upstream raw materials:

tetracyclo-[3.2.0.0.^2,7.0^4,6]heptane

2-nitrobenzenesulfenyl chloride

(1R,2S,4S,6R)-5-(2-Nitro-phenylsulfanyl)-tricyclo[2.2.1.0^2,6]heptan-3-one

(1R,2S,3S,4S,5R,6R)-5-(2-Nitro-phenylsulfanyl)-tricyclo[2.2.1.0^2,6]heptan-3-ol