trans-(p-tolyl-C*C-)2-tetrakis(trimethyl phosphite)ruthenium(II)

Base Information

• Chemical Name: trans-(p-tolyl-C*C-)2-tetrakis(trimethyl phosphite)ruthenium(II)
• CAS No.: 168062-79-1
• Molecular Formula: C₃₀H₅₀O₁₂P₄Ru
• Molecular Weight: 827.685
• Mol file: 168062-79-1.mol

Synonyms:

Chemical Property of trans-(p-tolyl-C*C-)2-tetrakis(trimethyl phosphite)ruthenium(II)

Chemical Property:

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Technology Process of trans-(p-tolyl-C*C-)2-tetrakis(trimethyl phosphite)ruthenium(II)

There total 1 articles about trans-(p-tolyl-C*C-)2-tetrakis(trimethyl phosphite)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

dichlorotetrakis(trimethyl phosphite)ruthenium(II) (61818-04-0,99096-00-1) + lithium (p-tolyl)acetylide (52999-17-4) → trans-(p-tolyl-C*C-)2-tetrakis(trimethyl phosphite)ruthenium(II) (168062-79-1)

Guidance literature:

In tetrahydrofuran; inert atmosphere; 4 equivs. of acetylide, refluxing for 15 min; evapn., trituration (MeOH or EtOH), collection (filtration), crystn. (EtOH:hexane, -20°C); elem. anal.;

DOI:10.1021/om00009a015

upstream raw materials:

dichlorotetrakis(trimethyl phosphite)ruthenium(II)

lithium (p-tolyl)acetylide