{N(PPh₃)2}2{(osmium)20(mercury)(C)2(carbonyl)48}

Base Information

• Chemical Name: {N(PPh₃)2}2{(osmium)20(mercury)(C)2(carbonyl)48}
• CAS No.: 106466-56-2
• Molecular Formula: 48CO*2C₃₆H₃₀NP₂*C₂HgOs₂₀
• Molecular Weight: 6450.29
• Mol file: 106466-56-2.mol

Synonyms:

Chemical Property of {N(PPh₃)2}2{(osmium)20(mercury)(C)2(carbonyl)48}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of {N(PPh₃)2}2{(osmium)20(mercury)(C)2(carbonyl)48}

There total 11 articles about {N(PPh₃)2}2{(osmium)20(mercury)(C)2(carbonyl)48} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

{N(PPh3)2}2{(osmium)20(mercury)2(C)2(carbonyl)48} (112595-82-1) → {N(PPh3)2}2{(osmium)20(mercury)(C)2(carbonyl)48} (106466-56-2) + mercury

Guidance literature:

In dichloromethane; Standing under N2 for 1 week, crystals are deposited along with Hg.; Elem. anal.;

DOI:10.1021/om00094a003

Reference yield: 70.0%

Os11CHg*27CO*C6Cl5(1-)*N(P(C6H5)3)2(1+)=(N(P(C6H5)3)2)(Os11C(CO)27(Hg(C6Cl5))) → {N(PPh3)2}2{(osmium)20(mercury)(C)2(carbonyl)48} (106466-56-2)

Guidance literature:

In dichloromethane; under nitrogen; standing (2 d, room temp.); elem. anal.;

DOI:10.1039/DT9890001455

Reference yield:

[N(PPh3)2]2[Os10C(CO)24] + pentafluorophenylmercury chloride (941-78-6) → {N(PPh3)2}2{(osmium)20(mercury)(C)2(carbonyl)48} (106466-56-2)

Guidance literature:

In dichloromethane; byproducts: Hg(C6F5)2; storage of intermediate soln. in CH2Cl2 for 1 wk; recrystn.;

DOI:10.1039/c39860000928

upstream raw materials:

pentafluorophenylmercury chloride

{N(PPh₃)2}2{(osmium)20(mercury)2(C)2(carbonyl)48}

Pentachlorphenyl-quecksilberchlorid

Hg(C₆Cl₅)(O₂CCF₃)