nickel(II) 2-(amidinium)ethynyl-5,10,15,20-tetramesitylporphyrin chloride

Base Information

• Chemical Name: nickel(II) 2-(amidinium)ethynyl-5,10,15,20-tetramesitylporphyrin chloride
• CAS No.: 956428-32-3
• Molecular Formula: C₅₉H₅₅N₆Ni*Cl
• Molecular Weight: 942.269
• Mol file: 956428-32-3.mol

Synonyms:

Chemical Property of nickel(II) 2-(amidinium)ethynyl-5,10,15,20-tetramesitylporphyrin chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of nickel(II) 2-(amidinium)ethynyl-5,10,15,20-tetramesitylporphyrin chloride

There total 1 articles about nickel(II) 2-(amidinium)ethynyl-5,10,15,20-tetramesitylporphyrin chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

amino(methyl)aluminum chloride (84738-98-7) + nickel(II) 2-(cyano)ethynyl-5,10,15,20-tetramesitylporphyrin (956428-31-2) → nickel(II) 2-(amidinium)ethynyl-5,10,15,20-tetramesitylporphyrin chloride (956428-32-3)

Guidance literature:

In toluene; Al compd. was added to soln. of Ni complex in toluene under N2; heated at 100°C for 5 d under N2; cooled to room temp.; poured onto slurry of silica gel in CHCl3; stirredin air for 10 min; filtered; filtrate concd. (vac.); chromd. (silica, C H2Cl2/CH3OH, 10/1);

DOI:10.1021/ic700838s

upstream raw materials:

amino(methyl)aluminum chloride

nickel(II) 2-(cyano)ethynyl-5,10,15,20-tetramesitylporphyrin