PPN[PtMe3(μ-pz)3]

Base Information

• Chemical Name: PPN[PtMe3(μ-pz)3]
• CAS No.: 1018685-02-3
• Molecular Formula: C₁₅H₂₇N₆Pt₂*C₃₆H₃₀NP₂
• Molecular Weight: 1220.17
• Mol file: 1018685-02-3.mol

Synonyms:

Chemical Property of PPN[PtMe3(μ-pz)3]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PPN[PtMe3(μ-pz)3]

There total 1 articles about PPN[PtMe3(μ-pz)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

[Me3Pt(acetone)3][BF4] (213213-60-6,201987-77-1) + [PtMe3(pzH)3]BF4 (1018684-99-5) + bis(triphenylphosphine)iminium chloride (21050-13-5) → PPN[PtMe3(μ-pz)3] (1018685-02-3)

Guidance literature:

With KOAc; In acetone; byproducts: KCl; under Ar, 1.2 equiv. of KOAc was added to 0.2 equiv. of acetone-complex in Me2CO, 0.2 equiv. of pyrazole-complex was added dropwise in Me2CO, 30min, filtration, evapn. to dryness in vac., extn. with CH2Cl2, extract was added to 0.2 equiv. of P-compd.; soln. was evapd., KCl was filtered off, pptg. by addn. of Et2O for 12 h,ppt. was filtered off, washed with n-pentane/CH2Cl2 (1/1) 3 times), dri ed in vac., elem. anal.;

DOI:10.1016/j.poly.2007.11.020

upstream raw materials:

[Me₃Pt(acetone)3][BF₄]

[PtMe₃(pzH)3]BF₄

bis(triphenylphosphine)iminium chloride