[Pt(IV)(4-trifluoromethylbenzoate)(2,6-(dimethylaminomethyl)phenyl(N,C,N))iodine(trimethylsilylalkynyl)] complex

Base Information

• Chemical Name: [Pt(IV)(4-trifluoromethylbenzoate)(2,6-(dimethylaminomethyl)phenyl(N,C,N))iodine(trimethylsilylalkynyl)] complex
• CAS No.: 858116-43-5
• Molecular Formula: C₂₅H₃₂F₃IN₂O₂PtSi
• Molecular Weight: 799.606
• Mol file: 858116-43-5.mol

Synonyms:

Chemical Property of [Pt(IV)(4-trifluoromethylbenzoate)(2,6-(dimethylaminomethyl)phenyl(N,C,N))iodine(trimethylsilylalkynyl)] complex

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pt(IV)(4-trifluoromethylbenzoate)(2,6-(dimethylaminomethyl)phenyl(N,C,N))iodine(trimethylsilylalkynyl)] complex

There total 1 articles about [Pt(IV)(4-trifluoromethylbenzoate)(2,6-(dimethylaminomethyl)phenyl(N,C,N))iodine(trimethylsilylalkynyl)] complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

[Pt(II)(4-trifluoromethylbenzoate)(2,6-(dimethylaminomethyl)phenyl-N,C,N)] complex (858116-44-6) + phenyl(trimethylsilylethynyl)iodonium triflate (133816-00-9) + sodium iodide (7681-82-5,24359-64-6,41927-88-2,115813-40-6) → [Pt(IV)(4-trifluoromethylbenzoate)(2,6-(dimethylaminomethyl)phenyl(N,C,N))iodine(trimethylsilylalkynyl)] complex (858116-43-5)

Guidance literature:

In acetone; Ar; addn. of IPh(C2SiMe3)OTf to Pt(O2CC6H4CF3)(NCN) compound in acetone,30 min stirring, addn. of NaI, further 30 min stirring; vac. evapn., extraction (CH2Cl2), filtration, vac. evapn., washing with cold Et2O;

DOI:10.1016/j.inoche.2004.11.001

upstream raw materials:

[Pt(II)(4-trifluoromethylbenzoate)(2,6-(dimethylaminomethyl)phenyl-N,C,N)] complex

phenyl(trimethylsilylethynyl)iodonium triflate

sodium iodide