dipotassium(nonacarbonyl-μ3-(phenylphosphinidene)triferrate(3Fe-Fe))

Base Information

Chemical Name:dipotassium(nonacarbonyl-μ3-(phenylphosphinidene)triferrate(3Fe-Fe))
CAS No.:108453-13-0
Molecular Formula:C₁₅H₅Fe₃O₉P*2K
Molecular Weight:605.911
Hs Code.:

Synonyms:

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Chemical Property of dipotassium(nonacarbonyl-μ3-(phenylphosphinidene)triferrate(3Fe-Fe))

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Technology Process of dipotassium(nonacarbonyl-μ3-(phenylphosphinidene)triferrate(3Fe-Fe))

There total 1 articles about dipotassium(nonacarbonyl-μ3-(phenylphosphinidene)triferrate(3Fe-Fe)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: {Fe₃H₂(CO)9(PC₆H₅)}

: potassium hydride

: 108453-13-0
dipotassium(nonacarbonyl-μ3-(phenylphosphinidene)triferrate(3Fe-Fe))

Guidance literature:: In tetrahydrofuran; Sonication; KH in freshly distilled THF is activated by an ultrasonic treatment for15 min, addn. of Fe-cluster, ultrasonic treatment of suspn. for 1 h (under exclusion of light); filtration, evapn. of solvent in vacuo, washing residue with hexane, drying in vacuo at 30°C;

Reference yield: 20.0%

: 108453-13-0
dipotassium(nonacarbonyl-μ3-(phenylphosphinidene)triferrate(3Fe-Fe))

: 2767-47-7
dimethyltin dibromide

: 108453-03-8
nonacarbonyl-μ2-(dimethylstannylene)-μ3-(phenylphosphinidene)triiron(3Fe-Fe)

Guidance literature:: In toluene; suspending K-salt in toluene by ultrasonic treatment, addn. of Me2SnBr2(under exclusion of light), stirring for 1 h; evapn. in vacuo, column chromy., elution with hexane yields orange fraction, recrystn. from pentane by cooling; elem. anal.;

Reference yield: 18.0%

: 108453-13-0
dipotassium(nonacarbonyl-μ3-(phenylphosphinidene)triferrate(3Fe-Fe))

: [Me₃PCuCl]₄

: {Fe₃H₂(CO)9(PC₆H₅)}

: 108453-05-0
nonacarbonylbis((trimethylphosphine)copper)-μ3-(phenylphosphinidene)triiron(Cu-Cu, 5Cu-Fe, 3Fe-Fe)

Guidance literature:: With AgClO₄; In tetrahydrofuran; addn. of solid phosphine-Cu-halogenide to a soln. of Fe-complex in THF (under exclusion of light, stirring), addn. of AgClO4 after 5 min, stirring for 30-60 min; evapn. of solvent in vacuo, column chromy., elution with hexane yields Fe-complex, elution (hexane/C6H6) yields product cluster, recrystn. (pentane/benzene), elem. anal.;