{Re(CNC₆H₅)6}⁽¹⁺⁾*PF₆^(1-)={Re(CNC₆H₅)6}PF₆

Base Information

Chemical Name:{Re(CNC₆H₅)6}⁽¹⁺⁾*PF₆^(1-)={Re(CNC₆H₅)6}PF₆
CAS No.:87829-81-0
Molecular Formula:C₄₂H₃₀N₆Re*F₆P
Molecular Weight:949.912
Hs Code.:

{Re(CNC<sub>6</sub>H<sub>5</sub>)6}<sup>(1+)</sup>*PF<sub>6</sub><sup>(1-)</sup>={Re(CNC<sub>6</sub>H<sub>5</sub>)6}PF<sub>6</sub>

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Chemical Property of {Re(CNC₆H₅)6}⁽¹⁺⁾*PF₆^(1-)={Re(CNC₆H₅)6}PF₆

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Technology Process of {Re(CNC₆H₅)6}⁽¹⁺⁾*PF₆^(1-)={Re(CNC₆H₅)6}PF₆

There total 4 articles about {Re(CNC₆H₅)6}⁽¹⁺⁾*PF₆^(1-)={Re(CNC₆H₅)6}PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 17084-13-8
potassium hexafluorophosphate

: 89308-97-4
{Re(CNC₆H₅)6}⁽¹⁺⁾*I₃^(1-)={Re(CNC₆H₅)6}I₃

: 87829-81-0
{Re(CNC₆H₅)6}⁽¹⁺⁾*PF₆^(1-)={Re(CNC₆H₅)6}PF₆

Guidance literature:: In acetone; addn. of KPF6 to soln. of Re complex and stirring for 1 h in the air; filtered soln. was evapd. to dryness, residue dissolved in CH2Cl2 and pptd. by addn. of PE; elem. anal.;
DOI:10.1016/S0022-328X(00)99328-8

Reference yield: 60.0%

: 17084-13-8
potassium hexafluorophosphate

: 33612-87-2,14126-96-6,15628-76-9
dirhenium(III) dichlorotetra-μ-acetate

: 1197040-29-1,931-54-4
phenyl isocyanate

: 87829-81-0
{Re(CNC₆H₅)6}⁽¹⁺⁾*PF₆^(1-)={Re(CNC₆H₅)6}PF₆

Guidance literature:: In methanol; under N2, phenyl isocyanide syringed into stirred suspn. of Re complex in methanol, mixt. refluxed for 6 h, soln. taken to dryness, satd. soln.of KPF6 in methanol added, mixt. stirred for 1 h; soln. taken to dryness, residue redissolved in 2-propanol, diethyl ether added dropwise until soln. clouded, soln. chilled, filtered, washed with diethyl ether, dried in vac.;

Reference yield: 57.0%

: 17084-13-8
potassium hexafluorophosphate

: (n-Bu₄N)2Re₂Cl₈

: 1197040-29-1,931-54-4
phenyl isocyanate

: 87829-81-0
{Re(CNC₆H₅)6}⁽¹⁺⁾*PF₆^(1-)={Re(CNC₆H₅)6}PF₆

Guidance literature:: In methanol; byproducts: KCl, C6H5NHCH=NPh; (N2); Re complex soln. treated with ligand, stirred at room temp. for 4h, refluxed for 1 h, evapd. at room temp. under N2, treated with KPF6 soln. in acetone; filtered, solid washed with acetone, filtrate and extracts evapd., washed with petroleum ether, then Et2O, extd. (CH2Cl2), pptd. (petroleum ether), recrystd. (acetone/Et2O, then CH2Cl2/petroleum ether); elem. anal.;
DOI:10.1021/om00080a014