cis-dichloro{3,11-dimethyl-3,11,17,18-tetraazatricyclo{11.3.1.1(5,9)}octadeca-1⁽¹⁷⁾,5,7,9⁽¹⁸⁾,13,15-hexaene}rhodium(III) tetraphenylborate*CH₃CN

Base Information

• Chemical Name: cis-dichloro{3,11-dimethyl-3,11,17,18-tetraazatricyclo{11.3.1.1(5,9)}octadeca-1⁽¹⁷⁾,5,7,9⁽¹⁸⁾,13,15-hexaene}rhodium(III) tetraphenylborate*CH₃CN
• CAS No.: 129551-33-3
• Molecular Formula: C₂H₃N*C₁₆H₂₀Cl₂N₄Rh*C₂₄H₂₀B
• Molecular Weight: 802.459
• Mol file: 129551-33-3.mol

Synonyms:

Chemical Property of cis-dichloro{3,11-dimethyl-3,11,17,18-tetraazatricyclo{11.3.1.1(5,9)}octadeca-1⁽¹⁷⁾,5,7,9⁽¹⁸⁾,13,15-hexaene}rhodium(III) tetraphenylborate*CH₃CN

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-dichloro{3,11-dimethyl-3,11,17,18-tetraazatricyclo{11.3.1.1(5,9)}octadeca-1⁽¹⁷⁾,5,7,9⁽¹⁸⁾,13,15-hexaene}rhodium(III) tetraphenylborate*CH₃CN

There total 1 articles about cis-dichloro{3,11-dimethyl-3,11,17,18-tetraazatricyclo{11.3.1.1(5,9)}octadeca-1⁽¹⁷⁾,5,7,9⁽¹⁸⁾,13,15-hexaene}rhodium(III) tetraphenylborate*CH₃CN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

rhodium(III) chloride trihydrate + sodium tetraphenyl borate (143-66-8) + 3,1-dimethyl-3,11,17,18-tetraazatricyclo[11.3.1.1(5,9)]octadeca-1(17),5(18),6,8,13,15-hexaene (115078-45-0) → cis-dichloro{3,11-dimethyl-3,11,17,18-tetraazatricyclo{11.3.1.1(5,9)}octadeca-1(17),5,7,9(18),13,15-hexaene}rhodium(III) tetraphenylborate*CH3CN (129551-33-3)

Guidance literature:

In methanol; heating a soln. of 3,11-dimethyl-3,11,17,18-tetraazatricyclo(11.3.1.1(5,9))octadeca-1(17),5,7,9(18),13,15-hexaene and RhCl3*3H2O for 2 h at 80°C, filtration, addn. of hot soln. of NaB(C6H5)4; pptn., recrystn. (CH3CN/benzene), elem. anal.;

DOI:10.1246/bcsj.63.1822

upstream raw materials:

sodium tetraphenyl borate

3,1-dimethyl-3,11,17,18-tetraazatricyclo[11.3.1.1(5,9)]octadeca-1⁽¹⁷⁾,5⁽¹⁸⁾,6,8,13,15-hexaene