tricarbonyl((1,2,3,4-η)-5α-(2'-formyl-5'-methoxyphenyl)-1,3-cyclohexadiene)iron(0)

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Chemical Name:tricarbonyl((1,2,3,4-η)-5α-(2'-formyl-5'-methoxyphenyl)-1,3-cyclohexadiene)iron(0)
CAS No.:557762-76-2
Molecular Formula:C₁₇H₁₄FeO₅
Molecular Weight:354.142
Hs Code.:

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Chemical Property of tricarbonyl((1,2,3,4-η)-5α-(2'-formyl-5'-methoxyphenyl)-1,3-cyclohexadiene)iron(0)

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Technology Process of tricarbonyl((1,2,3,4-η)-5α-(2'-formyl-5'-methoxyphenyl)-1,3-cyclohexadiene)iron(0)

There total 1 articles about tricarbonyl((1,2,3,4-η)-5α-(2'-formyl-5'-methoxyphenyl)-1,3-cyclohexadiene)iron(0) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

: 557762-74-0
tricarbonyl((1,2,3,4-η)-5α-[2'-(4'',4''-dimethyloxazolin-2''-yl)-5'-methoxyphenyl]-1,3-cyclohexadiene)iron(0)

: 557762-76-2
tricarbonyl((1,2,3,4-η)-5α-(2'-formyl-5'-methoxyphenyl)-1,3-cyclohexadiene)iron(0)

Guidance literature:: With hydrogenchloride; L-Selectride; methyl iodide; In acetone; (N2); reflux of Fe(CO)3(C18H21O2N), MeI in C3H6O for 4 h, removal of volatiles under reduced pressure, dissolving in CH2Cl2, cooling to -50°C, addn. of L-selectride, stirring for 1 h, warming to -10°C, addn. of HCl in EtOH, stirring for 1h; dilution with water, extn. with ether, drying of combined extracts over MgSO4, concd. under reduced pressure, chromy. on silica gel, elution with a mixt. of hexane/ethyl acetate (3:1), not isolated, identification byNMR;
DOI:10.1016/S0022-328X(02)02146-0