RuCo(CO)6(P(C₆H₅)2)(P(C₆H₅)3)

Base Information

• Chemical Name: RuCo(CO)6(P(C₆H₅)2)(P(C₆H₅)3)
• CAS No.: 82544-74-9
• Molecular Formula: C₃₆H₂₅CoO₆P₂Ru
• Molecular Weight: 775.602
• Mol file: 82544-74-9.mol

Synonyms:

Chemical Property of RuCo(CO)6(P(C₆H₅)2)(P(C₆H₅)3)

Chemical Property:

Purity/Quality:

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Technology Process of RuCo(CO)6(P(C₆H₅)2)(P(C₆H₅)3)

There total 2 articles about RuCo(CO)6(P(C₆H₅)2)(P(C₆H₅)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

(OC)4Ru(μ-PPh2)Co(CO)3 + 2,3-bis(diphenylphosphino)maleic anhydride (51501-24-7) → RuCo(CO)6(P(C6H5)2)(P(C6H5)3) (99094-58-3,82544-74-9,99094-59-4) + CoRu(CO)4P(C6H5)2C4O3(P(C6H5)2)2

Guidance literature:

In 1,2-dichloro-ethane; 1,2-dichloroethane soln. of CoRu-complex and ligand was heated overnightat reflux under Ar, cooled to room temp.; solvent was removed under vac., column chromy. over silica gel, eluted with petroleum ether/CH2Cl2; elem. anal.;

DOI:10.1021/ic991279r

Reference yield:

RuCo(P(C6H5)2)(CO)5(P(C6H5)3)2 (82544-73-8) → RuCo(CO)6(P(C6H5)2)(P(C6H5)3) (99094-58-3,82544-74-9,99094-59-4) + (OC)4Ru(μ-PPh2)Co(CO)3

Guidance literature:

With CO; In not given; stirred at 25°C under 1 atm of CO for 12 h; not isolated, detected by NMR;

upstream raw materials:

RuCo(P(C₆H₅)2)(CO)5(P(C₆H₅)3)2

2,3-bis(diphenylphosphino)maleic anhydride