4-{4-[4-bromo-2-(1H,1H,2H,2H,3H,3H-perfluoroundecyl)phenoxy]butyl}-2,2-dimethyl-1,3-dioxolane

Base Information

Chemical Name:4-{4-[4-bromo-2-(1H,1H,2H,2H,3H,3H-perfluoroundecyl)phenoxy]butyl}-2,2-dimethyl-1,3-dioxolane
CAS No.:1306771-51-6
Molecular Formula:C₂₆H₂₆BrF₁₇O₃
Molecular Weight:789.367
Hs Code.:

Synonyms:

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Chemical Property of 4-{4-[4-bromo-2-(1H,1H,2H,2H,3H,3H-perfluoroundecyl)phenoxy]butyl}-2,2-dimethyl-1,3-dioxolane

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Technology Process of 4-{4-[4-bromo-2-(1H,1H,2H,2H,3H,3H-perfluoroundecyl)phenoxy]butyl}-2,2-dimethyl-1,3-dioxolane

There total 5 articles about 4-{4-[4-bromo-2-(1H,1H,2H,2H,3H,3H-perfluoroundecyl)phenoxy]butyl}-2,2-dimethyl-1,3-dioxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

: 80331-52-8
4-(4-bromobutyl)-2,2-dimethyl-1,3-dioxolane

: 4-bromo-2-(1H,1H,2H,2H,3H,3H-perfluoroundecyl)phenol

: 1306771-51-6
4-{4-[4-bromo-2-(1H,1H,2H,2H,3H,3H-perfluoroundecyl)phenoxy]butyl}-2,2-dimethyl-1,3-dioxolane

Guidance literature:: With potassium carbonate; potassium iodide; In acetonitrile; for 2h; Reflux; Inert atmosphere;
DOI:10.1021/ja200822z

Reference yield:

: 507-63-1
1-iodoheptadecafluorooctane

: 1306771-51-6
4-{4-[4-bromo-2-(1H,1H,2H,2H,3H,3H-perfluoroundecyl)phenoxy]butyl}-2,2-dimethyl-1,3-dioxolane

Guidance literature:: Multi-step reaction with 4 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / hexane / 36 h / 0 - 25 °C / Inert atmosphere

2: lithium aluminium tetrahydride / diethyl ether / Reflux

3: hydrogen bromide; dimethyl sulfoxide / acetic acid / -5 - 10 °C

4: potassium carbonate; potassium iodide / acetonitrile / 2 h / Reflux; Inert atmosphere

With lithium aluminium tetrahydride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; hydrogen bromide; potassium carbonate; dimethyl sulfoxide; potassium iodide; In diethyl ether; hexane; acetic acid; acetonitrile;
DOI:10.1021/ja200822z

Reference yield:

: 1745-81-9
o-Allylphenol

: 1306771-51-6
4-{4-[4-bromo-2-(1H,1H,2H,2H,3H,3H-perfluoroundecyl)phenoxy]butyl}-2,2-dimethyl-1,3-dioxolane

Guidance literature:: Multi-step reaction with 4 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / hexane / 36 h / 0 - 25 °C / Inert atmosphere

2: lithium aluminium tetrahydride / diethyl ether / Reflux

3: hydrogen bromide; dimethyl sulfoxide / acetic acid / -5 - 10 °C

4: potassium carbonate; potassium iodide / acetonitrile / 2 h / Reflux; Inert atmosphere

With lithium aluminium tetrahydride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; hydrogen bromide; potassium carbonate; dimethyl sulfoxide; potassium iodide; In diethyl ether; hexane; acetic acid; acetonitrile;
DOI:10.1021/ja200822z