acetonitriletris(triphenylphosphine)copper(I) tetrafluoroborate

Base Information

• Chemical Name: acetonitriletris(triphenylphosphine)copper(I) tetrafluoroborate
• CAS No.: 152188-18-6
• Molecular Formula: BF₄*C₅₆H₄₈CuNP₃
• Molecular Weight: 978.276
• Mol file: 152188-18-6.mol

Synonyms:

Chemical Property of acetonitriletris(triphenylphosphine)copper(I) tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of acetonitriletris(triphenylphosphine)copper(I) tetrafluoroborate

There total 3 articles about acetonitriletris(triphenylphosphine)copper(I) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

tetrakis(acetonitrile)copper(I)tetrafluoroborate + triphenylphosphine (603-35-0) → acetonitriletris(triphenylphosphine)copper(I) tetrafluoroborate (152188-18-6)

Guidance literature:

In dichloromethane; addn. of PPh3 to a soln. of (Cu(MeCN)4))BF4 in CH2Cl2 under N2 and crystn. from CH2Cl2/Et2O; elem. anal.;

DOI:10.1016/S0277-5387(00)87175-2

Reference yield:

triphenylphosphine (603-35-0) → acetonitriletris(triphenylphosphine)copper(I) tetrafluoroborate (152188-18-6)

Guidance literature:

Multi-step reaction with 2 steps

1: water; ethanol

2: ethanol

In ethanol; water;

DOI:10.1039/b505200a

Reference yield:

copper(I) oxide + tetrafluoroboric acid + triphenylphosphine (603-35-0) + acetonitrile (75-05-8,26809-02-9) → acetonitriletris(triphenylphosphine)copper(I) tetrafluoroborate (152188-18-6)

Guidance literature:

In ethanol; water; acetonitrile; mixt. of Cu2O and PPh3 (P:Cu ratio 3:1) suspended in EtOH-MeCN; aq. HBF4added dropwise; warmed with stirring; crystd. by cooling and standing; elem. anal.;

DOI:10.1039/b505200a

upstream raw materials:

triphenylphosphine

acetonitrile

Downstream raw materials:

(tetrafluoroborato)tris(triphenylphosphine)copper(I)