[AlMe2(η2-N(N[2-(2,4,6-iPr3C6H2)C6H4])2)]

Base Information

• Chemical Name: [AlMe2(η2-N(N[2-(2,4,6-iPr3C6H2)C6H4])2)]
• CAS No.: 1243540-69-3
• Molecular Formula: C₄₄H₆₀AlN₃
• Molecular Weight: 657.962
• Mol file: 1243540-69-3.mol

Synonyms:

Chemical Property of [AlMe2(η2-N(N[2-(2,4,6-iPr3C6H2)C6H4])2)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [AlMe2(η2-N(N[2-(2,4,6-iPr3C6H2)C6H4])2)]

There total 8 articles about [AlMe2(η2-N(N[2-(2,4,6-iPr3C6H2)C6H4])2)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

[2-(2,4,6-iPr3C6H2)C6H4]NNNH[2-(2,4,6-iPr3C6H2)C6H4] (1023925-82-7,909121-88-6) + trimethylaluminum (75-24-1) → [AlMe2(η2-N(N[2-(2,4,6-iPr3C6H2)C6H4])2)] (1243540-69-3)

Guidance literature:

In hexane; byproducts: CH4; (inert atm., glovebox); addn. of aluminium compd. to hexane suspn. of triazenido deriv., stirring for 0.5 h at room temp.; drying in vac., elem. anal.;

DOI:10.1039/b925837j

Reference yield: 51.0%

lanthanum(III) tetramethylaluminate + K[2-(2,4,6-iPr3C6H2)C6H4]NNN[2-(2,4,6-iPr3C6H2)C6H4] → [AlMe2(η2-N(N[2-(2,4,6-iPr3C6H2)C6H4])2)] (1243540-69-3) + [La(η2-tetramethylaluminate)2(η2-N(N[2-(2,4,6-iPr3C6H2)C6H4])2)]

Guidance literature:

In toluene; byproducts: KAl(CH3)4; (inert atm., glovebox); addn. of toluene suspn. of triazenido deriv. to toluene soln. of lanthanum compd., stirring for 2 h at room temp.; centrifugation, washing with toluene, evapn. of toluene solns. in vac., elem. anal.;

DOI:10.1039/b925837j

Reference yield: 49.0%

lanthanum(III) tetramethylaluminate + [2-(2,4,6-iPr3C6H2)C6H4]NNNH[2-(2,4,6-iPr3C6H2)C6H4] (1023925-82-7,909121-88-6) → [AlMe2(η2-N(N[2-(2,4,6-iPr3C6H2)C6H4])2)] (1243540-69-3) + [La(η2-tetramethylaluminate)2(η2-N(N[2-(2,4,6-iPr3C6H2)C6H4])2)]

Guidance literature:

In hexane; byproducts: CH4, Al(CH3)3; (inert atm., glovebox); addn. of hexane suspn. of triazenido deriv. to hexane soln. of lanthanum compd., stirring for 0.5-1 h at room temp.; drying in vac., elem. anal.;

DOI:10.1039/b925837j

upstream raw materials:

[2-(2,4,6-iPr₃C₆H₂)C₆H₄]NNNH[2-(2,4,6-iPr₃C₆H₂)C₆H₄]

trimethylaluminum