(η5-C5H4CH2C6H4-2-OMe)2VCl2

Base Information

• Chemical Name: (η5-C5H4CH2C6H4-2-OMe)2VCl2
• CAS No.: 1310429-65-2
• Molecular Formula: C₂₆H₂₆Cl₂O₂V
• Molecular Weight: 492.339
• Mol file: 1310429-65-2.mol

Synonyms:

Chemical Property of (η5-C5H4CH2C6H4-2-OMe)2VCl2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (η5-C5H4CH2C6H4-2-OMe)2VCl2

There total 1 articles about (η5-C5H4CH2C6H4-2-OMe)2VCl2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 17.0%

tris(acetylacetonato)vanadium(III) (13476-99-8) + (2-methoxybenzyl)cyclopentadiene (1310429-67-4) + phosphorus trichloride (7719-12-2,52843-90-0) → (η5-C5H4CH2C6H4-2-OMe)2VCl2 (1310429-65-2)

Guidance literature:

With MeMgCl; In tetrahydrofuran; N2; MeMgCl in THF added dropwise to THF soln. of ligand, stirred overnight, added to THF suspn. of V(acac)3 cooled to -78°C (2:2:1 molar ratio), mixt. stirred for 1 h at room temp., refluxed for 30 min, extd. Et2O, treated with PCl3 (2 equiv.); mixt. stirred overnight, ppt. filtered off, washed (Et2O), recrystd. (DCM/hexane), elem. anal.;

DOI:10.1016/j.ica.2011.03.034

upstream raw materials:

tris(acetylacetonato)vanadium(III)

(2-methoxybenzyl)cyclopentadiene

phosphorus trichloride