{(CO)4{((CH₃)2C₆H₃O)3P}Fe}

Base Information

Chemical Name:{(CO)4{((CH₃)2C₆H₃O)3P}Fe}
CAS No.:92641-78-6
Molecular Formula:C₂₈H₂₇FeO₇P
Molecular Weight:562.339
Hs Code.:

{(CO)4{((CH<sub>3</sub>)2C<sub>6</sub>H<sub>3</sub>O)3P}Fe}

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Chemical Property of {(CO)4{((CH₃)2C₆H₃O)3P}Fe}

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Technology Process of {(CO)4{((CH₃)2C₆H₃O)3P}Fe}

There total 1 articles about {(CO)4{((CH₃)2C₆H₃O)3P}Fe} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 36432-47-0
tris(3,5-dimethylphenyl) phosphite

: 92641-78-6
{(CO)4{((CH₃)2C₆H₃O)3P}Fe}

Guidance literature:: With LiAlH₄; In tetrahydrofuran; under N2, reflux for 5 days; filtration, column chromy. (alumina, hexane), crystd. from hexane at -20°C;

Reference yield: 90.0%

: potassium tri(isopropoxy)borohydride

: 92641-78-6
{(CO)4{((CH₃)2C₆H₃O)3P}Fe}

: 71-91-0
tetraethylammonium bromide

: 70459-98-2
(CH₃CH₂)4N⁽¹⁺⁾*{(CO)3{((CH₃)2C₆H₃O)3P}Fe(CHO)}^(1-)=(CH₃CH₂)4N{(CO)3{((CH₃)2C₆H₃O)3P}Fe(CHO)}

Guidance literature:: In tetrahydrofuran; KHB(OCH(CH3)2)3 was added to a flask in THF, solvent removed, Fe-complex and N(CH2CH3)4NBr was added in THF, stirred for 40 min under N2; NaOH was added(gas evolution), THF was removed, Et2O was added, stirred rapidly, H2O and ether were removed, the remaining solid was washed twice with ether, dried in vac.;

Reference yield: 74.0%

: 92641-78-6
{(CO)4{((CH₃)2C₆H₃O)3P}Fe}

: 71-91-0
tetraethylammonium bromide

: 917-54-4
methyllithium

: 92641-77-5
(CH₃CH₂)4N⁽¹⁺⁾*{(CO)3{((CH₃)2C₆H₃O)3P}Fe(COCH₃)}^(1-)={(CH₃CH₂)4N}{(CO)3{((CH₃)2C₆H₃O)3P}Fe}(COCH₃)

Guidance literature:: In diethyl ether; addn. of an ether soln. of MeLi at -72°C to Fe-complex, stirring for 30 min at 0°C, addn. of N(CH2CH3)4Br in aq. NaOH;; pptn.; filtn., washed with H2O and hexane, dried in vac., elem. anal.;