Benzoic acid, 2,4-dimethoxy-6-[(phenylthio)methyl]-, 4-[2-(4-hydroxybutyl)-1,3-dioxolan-2-yl]-1-methylbutyl ester, (S)-

Base Information

• Chemical Name: Benzoic acid, 2,4-dimethoxy-6-[(phenylthio)methyl]-, 4-[2-(4-hydroxybutyl)-1,3-dioxolan-2-yl]-1-methylbutyl ester, (S)-
• CAS No.: 139219-44-6
• Molecular Formula: C28H38O7S
• Molecular Weight: 518.672
• Mol file: 139219-44-6.mol

Synonyms:

Chemical Property of Benzoic acid, 2,4-dimethoxy-6-[(phenylthio)methyl]-, 4-[2-(4-hydroxybutyl)-1,3-dioxolan-2-yl]-1-methylbutyl ester, (S)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzoic acid, 2,4-dimethoxy-6-[(phenylthio)methyl]-, 4-[2-(4-hydroxybutyl)-1,3-dioxolan-2-yl]-1-methylbutyl ester, (S)-

There total 1 articles about Benzoic acid, 2,4-dimethoxy-6-[(phenylthio)methyl]-, 4-[2-(4-hydroxybutyl)-1,3-dioxolan-2-yl]-1-methylbutyl ester, (S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Methyl-5-oxonon-8-enyl 2,4-Dimethoxy-6-(phenylthiomethyl)benzoate (139219-43-5) → 4-<2-(4-Hydroxybutyl)-1,3-dioxolan-2-yl>-1-methylbutyl 2,4-Dimethoxy-6-(phenylthiomethyl)benzoate (139219-44-6)

Guidance literature:

With sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide; Yield given. Multistep reaction; 1.) THf, 40 deg C, 30 min, 2.) methanol, 60 deg C, 1 h;

Reference yield: 92.0%

4-<2-(4-Hydroxybutyl)-1,3-dioxolan-2-yl>-1-methylbutyl 2,4-Dimethoxy-6-(phenylthiomethyl)benzoate (139219-44-6) + p-toluenesulfonyl chloride (98-59-9) → 1-Methyl-4-<2-<4-(p-tolylsulphonyloxy)butyl>-1,3-dioxolan-2-yl>butyl 2,4-Dimethoxy-6-(phenylthiomethyl)benzoate (139219-45-7)

Guidance literature:

With pyridine; triethylamine; at 0 ℃; for 2h;

upstream raw materials:

1-Methyl-5-oxonon-8-enyl 2,4-Dimethoxy-6-(phenylthiomethyl)benzoate

Downstream raw materials:

1-Methyl-4-<2-<4-(p-tolylsulphonyloxy)butyl>-1,3-dioxolan-2-yl>butyl 2,4-Dimethoxy-6-(phenylthiomethyl)benzoate