trans-[Cr(1,4,8,11-tetraazacyclotetradecane)(CCC₆D₅)2]OTf

Base Information

• Chemical Name: trans-[Cr(1,4,8,11-tetraazacyclotetradecane)(CCC₆D₅)2]OTf
• CAS No.: 1333387-53-3
• Molecular Formula: CF₃O₃S*C₂₆H₃₄CrN₄
• Molecular Weight: 613.57
• Mol file: 1333387-53-3.mol

Synonyms:

Chemical Property of trans-[Cr(1,4,8,11-tetraazacyclotetradecane)(CCC₆D₅)2]OTf

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of trans-[Cr(1,4,8,11-tetraazacyclotetradecane)(CCC₆D₅)2]OTf

There total 1 articles about trans-[Cr(1,4,8,11-tetraazacyclotetradecane)(CCC₆D₅)2]OTf which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cis-[Cr(cyclam)(CF3SO3)2]CF3SO3 (482305-57-7,362054-73-7) + phenylacetylene-d6 (25837-47-2) → trans-[Cr(1,4,8,11-tetraazacyclotetradecane)(CCC6D5)2]OTf (1333387-53-3)

Guidance literature:

With C₄H₉Li; In tetrahydrofuran; hexane; (Ar); mixt. of metal complex and acetylene in THF was cooled in dry ice/acetone for 10 min, treated with 2.5 M n-BuLi in hexane, stirred in cold bath for 5 min, warmed to room temp. with stirring for 2 h; quenched with water, chromy. (silica, CH2Cl2/MeCN, 7:3, v/v), evapd. in vac., washed with Et2O, filtered, dried in vac., dissolved in THF, precipitated with Et2O, filtered;

DOI:10.1021/ic2009336

upstream raw materials:

cis-[Cr(cyclam)(CF₃SO₃)2]CF₃SO₃

phenylacetylene-d6