bis(triphenylphosphine)(bis(N-phthalimide))palladium(II)

Base Information

• Chemical Name: bis(triphenylphosphine)(bis(N-phthalimide))palladium(II)
• CAS No.: 824975-93-1
• Molecular Formula: C₅₂H₃₈N₂O₄P₂Pd
• Molecular Weight: 923.252
• Mol file: 824975-93-1.mol

Synonyms:

Chemical Property of bis(triphenylphosphine)(bis(N-phthalimide))palladium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(triphenylphosphine)(bis(N-phthalimide))palladium(II)

There total 3 articles about bis(triphenylphosphine)(bis(N-phthalimide))palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

[Pd(phthalimidate)2(SMe2)2] (1351023-42-1) + triphenylphosphine (603-35-0) → bis(triphenylphosphine)(bis(N-phthalimide))palladium(II) (824975-93-1)

Guidance literature:

In dichloromethane; P(C6H5)3 added to CH2Cl2 soln. of Pd-complex, refluxed for 1 h; concd., Et2O added, filtered, washed with Et2O, air dried; elem. anal.;

Reference yield: 78.5%

tetrakis(triphenylphosphine) palladium(0) (14221-01-3) + phthalimide (136918-14-4,85-41-6) → bis(triphenylphosphine)(bis(N-phthalimide))palladium(II) (824975-93-1)

Guidance literature:

In benzene; under Ar or N2; N-phthalimide (0.294 mmol) added to soln. of (Ph3P)4Pd (0.147 mmol) in dry C6H6; kept (12 h); solid filtered off; washed with C6H6; dried (vac.); recrystd. from CH2Cl2/ether (1/5 v/v); elem. anal.;

DOI:10.1016/j.molcata.2004.05.008

Reference yield:

phthalimide (136918-14-4,85-41-6) → bis(triphenylphosphine)(bis(N-phthalimide))palladium(II) (824975-93-1)

Guidance literature:

Multi-step reaction with 2 steps

2: dichloromethane

In dichloromethane;

upstream raw materials:

tetrakis(triphenylphosphine) palladium⁽⁰⁾

phthalimide

[Pd(phthalimidate)2(SMe₂)2]

triphenylphosphine