barium metaborate metaphosphate

Base Information

• Chemical Name: barium metaborate metaphosphate
• CAS No.: 12045-29-3
• Molecular Formula: BBaO₅P
• Molecular Weight: 259.112
• Mol file: 12045-29-3.mol

Synonyms:Bariumborate phosphate (2BaO.B2O3.P2O5) (8CI); Boron barium oxide phosphate, BaBPO5

Chemical Property of barium metaborate metaphosphate

Chemical Property:

• PSA: 131.47000
• LogP: -0.38130

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of barium metaborate metaphosphate

There total 4 articles about barium metaborate metaphosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ammonium dihydrogen phosphate (7722-76-1,10124-31-9,10361-65-6,7783-28-0) + boric acid (11113-50-1,14635-83-7) + barium carbonate → Ba-borophosphate (12045-29-3)

Guidance literature:

In neat (no solvent); byproducts: CO2, NH3, H2O; starting materials mixed in stoichiometric proportion , packed into crucible, temp. raised to 500°C, preheated at 500°C for 10 h, cooled to room temp., heated to 700°C for 24 h, cooled to room temp.; purity checked by X-ray powder diffraction, solid products pulverized, ground into fine powder;

DOI:10.1246/cl.2001.628

Reference yield:

boron trioxide + phosphorus pentoxide + barium(II) oxide → Ba-borophosphate (12045-29-3)

Guidance literature:

In hydrogenchloride; High Pressure; BaO/B2O3/P2O5 = 1:1:1; reaction in autoclave in 0.5 M HCl (T = 280°C, P = 100 bar, 20 d);

DOI:10.1016/S0925-8388(01)02017-5

Reference yield:

ammonium dihydrogen phosphate (10124-31-9,10361-65-6,7783-28-0) + boric acid (11113-50-1,14635-83-7) + barium carbonate → Ba-borophosphate (12045-29-3)

Guidance literature:

at 900 ℃; for 48h;

DOI:10.1039/c4tc02443e

upstream raw materials:

boric acid

ammonium dihydrogen phosphate

ammonium dihydrogen phosphate

Refernces

• 1、 Shi, Ying,Liang, Jingkui,Yang, Jinling,Zhuang, Weidong,Rao, Guanghui. "Subsolidus phase relations in the system BaO-B2O3-P2O5". . p. L1-L3. Retrieved 1997.
• 2、 Lei, Bing-Hua,Jing, Qun,Yang, Zhihua,Zhang, Bingbing,Pan, Shilie. "Anomalous second-harmonic generation response in SrBPO5 and BaBPO5". . p. 1557 - 1566. Retrieved 2015.