Nonanal, 9-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-

Base Information

Chemical Name:Nonanal, 9-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-
CAS No.:139258-86-9
Molecular Formula:C25H36O2Si
Molecular Weight:396.645
Hs Code.:

Synonyms:

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Chemical Property of Nonanal, 9-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-

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Technology Process of Nonanal, 9-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-

There total 8 articles about Nonanal, 9-[[(1,1-dimethylethyl)diphenylsilyl]oxy]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 139258-85-8
9-(tert-butyldiphenylsilyloxy)-nonan-1-ol

: 139258-86-9
9-(tert-butyldiphenylsilanyloxy)-nonanal

Guidance literature:: 9-(tert-butyldiphenylsilyloxy)-nonan-1-ol; With oxalyl dichloride; dimethyl sulfoxide; In dichloromethane; at -78 ℃; for 0.333333h; Inert atmosphere;

With triethylamine; In dichloromethane; at -78 - 20 ℃; for 0.5h; Inert atmosphere;
DOI:10.1021/tx300315h

Reference yield: 83.0%

: 207512-06-9
9-((1,1-dimethylethyl)diphenylsilyloxy)nonaoic acid methyl ester

: 139258-86-9
9-(tert-butyldiphenylsilanyloxy)-nonanal

Guidance literature:: With diisobutylaluminium hydride; In toluene; at -78 ℃; for 4h;
DOI:10.1021/ol060221v

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 139258-86-9
9-(tert-butyldiphenylsilanyloxy)-nonanal

Guidance literature:: Multi-step reaction with 5 steps

1: 48 percent / imidazole / tetrahydrofuran / 9 h / 20 °C

2: 90 percent / oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / -78 - 0 °C

3: 85 percent / toluene / 4 h / 80 °C

4: 80 percent / H₂ / Pd/C / methanol / 0.5 h

5: 83 percent / DIBALH / toluene / 4 h / -78 °C

With 1H-imidazole; oxalyl dichloride; hydrogen; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; toluene; 2: Swern oxidation;
DOI:10.1021/ol060221v