Technology Process of C41H44O12
There total 11 articles about C41H44O12 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C33H52O9Si;
With
1H-imidazole; tert-butyldimethylsilyl chloride;
In
dichloromethane;
at 20 ℃;
bis(trichloromethyl) carbonate;
With
pyridine;
In
dichloromethane;
at 20 ℃;
p-Anisaldehyde dimethyl acetal;
Further stages;
DOI:10.1038/nchem.1074
- Guidance literature:
-
Multi-step reaction with 9 steps
1.1: 122 °C / neat (no solvent)
1.2: 20 °C
2.1: 1,2-dichloro-benzene / 250 °C / Microwave irradiation
3.1: iodine; magnesium / diethyl ether / 0 °C
4.1: pyridine; dibromo sulfoxide / diethyl ether / -40 °C
5.1: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran / 0 °C
6.1: methyllithium lithium bromide / tetrahydrofuran / -78 - 20 °C
7.1: tris(dibenzylideneacetone)dipalladium(0) chloroform complex; formic acid / toluene / 20 °C
8.1: ozone / methanol; dichloromethane / -78 °C
8.2: -78 - 20 °C
9.1: 1H-imidazole; tert-butyldimethylsilyl chloride / dichloromethane / 20 °C
9.2: 20 °C
With
pyridine; 1H-imidazole; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; dibromo sulfoxide; formic acid; methyllithium lithium bromide; tetrabutyl ammonium fluoride; iodine; ozone; magnesium; tert-butyldimethylsilyl chloride; acetic acid;
In
tetrahydrofuran; methanol; diethyl ether; dichloromethane; 1,2-dichloro-benzene; toluene;
1.1: Claisen rearrangement;
DOI:10.1038/nchem.1074
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: ozone / methanol; dichloromethane / -78 °C
1.2: -78 - 20 °C
2.1: 1H-imidazole; tert-butyldimethylsilyl chloride / dichloromethane / 20 °C
2.2: 20 °C
With
1H-imidazole; ozone; tert-butyldimethylsilyl chloride;
In
methanol; dichloromethane;
DOI:10.1038/nchem.1074
