[RuBr(PPh₃)(N,N'-bis(2-hydroxy-1-naphthaldehyde) o-phenylene diamine(-2H))]

Base Information

• Chemical Name: [RuBr(PPh₃)(N,N'-bis(2-hydroxy-1-naphthaldehyde) o-phenylene diamine(-2H))]
• CAS No.: 737784-26-8
• Molecular Formula: C₄₆H₃₃BrN₂O₂PRu
• Molecular Weight: 857.728
• Mol file: 737784-26-8.mol

Synonyms:

Chemical Property of [RuBr(PPh₃)(N,N'-bis(2-hydroxy-1-naphthaldehyde) o-phenylene diamine(-2H))]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [RuBr(PPh₃)(N,N'-bis(2-hydroxy-1-naphthaldehyde) o-phenylene diamine(-2H))]

There total 2 articles about [RuBr(PPh₃)(N,N'-bis(2-hydroxy-1-naphthaldehyde) o-phenylene diamine(-2H))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

[bis(triphenylphosphine) (methanol) ruthenium(III) tribromide] (50492-98-3,15692-71-4) + N,N-bis(1-naphthaldimine)-o-phenylenediamine (33215-85-9) → [RuBr(PPh3)(N,N'-bis(2-hydroxy-1-naphthaldehyde) o-phenylene diamine(-2H))] (737784-26-8)

Guidance literature:

In benzene; elem. anal.;

DOI:10.1016/j.inoche.2003.11.020

Reference yield: 75.0%

[RuBr3(PPh3)3(MeOH)] + N,N-bis(1-naphthaldimine)-o-phenylenediamine (33215-85-9) → [RuBr(PPh3)(N,N'-bis(2-hydroxy-1-naphthaldehyde) o-phenylene diamine(-2H))] (737784-26-8)

Guidance literature:

In benzene; ligand added to a soln. of Ru complex, refluxed for 5 h; concd., pptd. (petroleum ether), recrystd. (CH2Cl2/petroleum ether); elem. anal.;

DOI:10.1016/j.ica.2005.11.028

upstream raw materials:

N,N-bis(1-naphthaldimine)-o-phenylenediamine

[bis(triphenylphosphine) (methanol) ruthenium(III) tribromide]