1-(α-C,α'-bromo-o-xylyl)-2-(tert-butyldimethylsilyl)-1,2-dicarba-closo-dodecaborane

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Chemical Name:1-(α-C,α'-bromo-o-xylyl)-2-(tert-butyldimethylsilyl)-1,2-dicarba-closo-dodecaborane
CAS No.:419562-80-4
Molecular Formula:C₁₆H₃₃B₁₀BrSi
Molecular Weight:441.538
Hs Code.:

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Chemical Property of 1-(α-C,α'-bromo-o-xylyl)-2-(tert-butyldimethylsilyl)-1,2-dicarba-closo-dodecaborane

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Technology Process of 1-(α-C,α'-bromo-o-xylyl)-2-(tert-butyldimethylsilyl)-1,2-dicarba-closo-dodecaborane

There total 1 articles about 1-(α-C,α'-bromo-o-xylyl)-2-(tert-butyldimethylsilyl)-1,2-dicarba-closo-dodecaborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 361544-93-6
1-lithio-2-tert-butyldimethylsilyl-1,2-dicarba-closo-dodecaborane⁽¹²⁾

: 91-13-4
α,α'-dibromo-o-xylene

: 419562-80-4
1-(α-C,α'-bromo-o-xylyl)-2-(tert-butyldimethylsilyl)-1,2-dicarba-closo-dodecaborane

Guidance literature:: In diethyl ether; benzene; to soln. Li(tBuMe2Si-1,2-C2B10H10) in benzene-Et2O (2:1) at 0°C was added dropwise soln. α,α'-dibromo-o-xylene in benzene-Et2O (2:1), allowed to warm to room temp. and refluxed for 12 h; soln. was evapd. to dryness in vacuo, residue was triturated with EtOH, cooled to -10°C overnight, ppt. was filtered, washed with chilledMeOh and dried in vacuo; elem. anal.;
DOI:10.1039/b107276e