1,1'-bis(p-xylylaminomethyl)ferrocene

Base Information

• Chemical Name: 1,1'-bis(p-xylylaminomethyl)ferrocene
• CAS No.: 863671-04-9
• Molecular Formula: C₂₈H₃₂FeN₂
• Molecular Weight: 452.422
• Mol file: 863671-04-9.mol

Synonyms:

Chemical Property of 1,1'-bis(p-xylylaminomethyl)ferrocene

Chemical Property:

Purity/Quality:

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Technology Process of 1,1'-bis(p-xylylaminomethyl)ferrocene

There total 1 articles about 1,1'-bis(p-xylylaminomethyl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

sodium tetrahydroborate (16940-66-2) + 1,1'-bis(p-xylyliminomethyl)ferrocene → 1,1'-bis(p-xylylaminomethyl)ferrocene (863671-04-9)

Guidance literature:

In tetrahydrofuran; methanol; to soln. 1,1'-bis(p-xylylaminomethyl)ferrocene in THF-MeOH, NaBH4 was added and stirred for 2+24 h at room temp.; react. mixt. was quenched with 1 N HCl, solvent was evapd., residue was partitioned between 2 N KOH and CH2Cl2, org. layer was dried iver MgSO4,filtered, and concd. in vacuo; elem. anal.;

DOI:10.1021/ic050215f

Reference yield: 69.0%

hydrogenchloride (7647-01-0,15364-23-5) + ammonium hexafluorophosphate + 1,1'-bis(p-xylylaminomethyl)ferrocene (863671-04-9) → Fe(C5H4CH2NH2CH2C6H4CH3)2(2+)*2PF6(1-)=(Fe(C5H4CH2NH2CH2C6H4CH3)2)(PF6)2

Guidance literature:

In hydrogenchloride; suspn. ferrocene in 6 M HCl was stirred for 13 h at room temp., solvent was evapd., residue was washed with water, suspended in acetone, NH4PF6 was added and stirred for 4 h at room temp.; soln. was filtered and evapd.; elem. anal.;

DOI:10.1021/ic050215f

upstream raw materials:

sodium tetrahydroborate