{(1,2,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene}{P,O-diphenyl-(R)-(4-methylphenylsulphinylmethyl)phosphine}rhodium(I) trifluoromethanesulphonate

Base Information

Chemical Name:{(1,2,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene}{P,O-diphenyl-(R)-(4-methylphenylsulphinylmethyl)phosphine}rhodium(I) trifluoromethanesulphonate
CAS No.:123283-71-6
Molecular Formula:CF₃O₃S*C₂₇H₂₇OPRhS
Molecular Weight:682.526
Hs Code.:

{(1,2,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene}{P,O-diphenyl-(R)-(4-methylphenylsulphinylmethyl)phosphine}rhodium(I) trifluoromethanesulphonate

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Chemical Property of {(1,2,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene}{P,O-diphenyl-(R)-(4-methylphenylsulphinylmethyl)phosphine}rhodium(I) trifluoromethanesulphonate

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Technology Process of {(1,2,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene}{P,O-diphenyl-(R)-(4-methylphenylsulphinylmethyl)phosphine}rhodium(I) trifluoromethanesulphonate

There total 1 articles about {(1,2,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene}{P,O-diphenyl-(R)-(4-methylphenylsulphinylmethyl)phosphine}rhodium(I) trifluoromethanesulphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: (bicyclo[2.2.1]hepta-2,5-diene)-(2,4-pentanedionato)rhodium (I)

: 219904-60-6
R-(+)-diphenyl(4-methylphenylsulphinylmethyl)phosphine

: 27607-77-8
trimethylsilyl trifluoromethanesulfonate

: 123283-71-6
{(1,2,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene}{P,O-diphenyl-(R)-(4-methylphenylsulphinylmethyl)phosphine}rhodium(I) trifluoromethanesulphonate

Guidance literature:: In tetrahydrofuran; under argon, Me3SiOSO2CF3 and (nbd)Rh(acac) in THF stirred for 5 min, Ph2PCH2S(O)Tol added, stirred for 1 h at 25°C, then added to vigorously-agitated hexane, most of the liquid removed by cannula, hexane added; filtered, dried; IR, NMR, mass spectra;
DOI:10.1016/0022-328X(88)83094-8

Reference yield:

: 219904-60-6
R-(+)-diphenyl(4-methylphenylsulphinylmethyl)phosphine

: 123283-71-6
{(1,2,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene}{P,O-diphenyl-(R)-(4-methylphenylsulphinylmethyl)phosphine}rhodium(I) trifluoromethanesulphonate

: 123302-78-3
bis{P,O-diphenyl-(R)-(4-methylphenylsulphinylmethyl)phosphine}rhodium(I) trifluoromethanesulphonate

Guidance literature:: In tetrahydrofuran; inert atmosphere, educts in THF precooled to -78°C mixed dropwise, stirred for 20 min at -78°C, warmed to 25°C during 10 min,; transferred to an NMR tube; NMR; mixt. (meso- and dl-isomer);;
DOI:10.1016/0022-328X(88)83094-8